{"title":"聚合物膜固定分子形式罗丹明B的吸收光谱和折射率与水中铅离子浓度的关系","authors":"I. Yu. Denisyuk, A. A. Rybikov, Yu. A. Ignat’eva","doi":"10.1134/S0030400X21040081","DOIUrl":null,"url":null,"abstract":"<p>The dependences of the adsorption and refractometric parameters of a polymer composition containing Rhodamine B in the molecular state on the concentration of lead atoms are studied. These dependences are used as a basis of an express-method of determining the concentration of lead ions in water, the sensitivity of which is shown to be as high as 0.001 mg/L, which is below the maximum permissible concentration. The use of the water-insoluble dye as a material sensitive to lead ions shows the possibility of developing a stable sensor based on the effect under study. The use of the frustrated total internal reflection method for determining the lead concentration by the aforementioned optical parameters is considered.</p>","PeriodicalId":723,"journal":{"name":"Optics and Spectroscopy","volume":"129 4","pages":"471 - 475"},"PeriodicalIF":0.8000,"publicationDate":"2022-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Dependences of the Optical Absorption Spectra and Refractive Index of Rhodamine B in Molecular Form Immobilized in a Polymer Film on the Concentration of Lead Ions in Water\",\"authors\":\"I. Yu. Denisyuk, A. A. Rybikov, Yu. A. Ignat’eva\",\"doi\":\"10.1134/S0030400X21040081\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The dependences of the adsorption and refractometric parameters of a polymer composition containing Rhodamine B in the molecular state on the concentration of lead atoms are studied. These dependences are used as a basis of an express-method of determining the concentration of lead ions in water, the sensitivity of which is shown to be as high as 0.001 mg/L, which is below the maximum permissible concentration. The use of the water-insoluble dye as a material sensitive to lead ions shows the possibility of developing a stable sensor based on the effect under study. The use of the frustrated total internal reflection method for determining the lead concentration by the aforementioned optical parameters is considered.</p>\",\"PeriodicalId\":723,\"journal\":{\"name\":\"Optics and Spectroscopy\",\"volume\":\"129 4\",\"pages\":\"471 - 475\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2022-01-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Optics and Spectroscopy\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0030400X21040081\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"OPTICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Optics and Spectroscopy","FirstCategoryId":"101","ListUrlMain":"https://link.springer.com/article/10.1134/S0030400X21040081","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"OPTICS","Score":null,"Total":0}
Dependences of the Optical Absorption Spectra and Refractive Index of Rhodamine B in Molecular Form Immobilized in a Polymer Film on the Concentration of Lead Ions in Water
The dependences of the adsorption and refractometric parameters of a polymer composition containing Rhodamine B in the molecular state on the concentration of lead atoms are studied. These dependences are used as a basis of an express-method of determining the concentration of lead ions in water, the sensitivity of which is shown to be as high as 0.001 mg/L, which is below the maximum permissible concentration. The use of the water-insoluble dye as a material sensitive to lead ions shows the possibility of developing a stable sensor based on the effect under study. The use of the frustrated total internal reflection method for determining the lead concentration by the aforementioned optical parameters is considered.
期刊介绍:
Optics and Spectroscopy (Optika i spektroskopiya), founded in 1956, presents original and review papers in various fields of modern optics and spectroscopy in the entire wavelength range from radio waves to X-rays. Topics covered include problems of theoretical and experimental spectroscopy of atoms, molecules, and condensed state, lasers and the interaction of laser radiation with matter, physical and geometrical optics, holography, and physical principles of optical instrument making.