A. Gowdhaman , S. Arun Kumar , D. Elumalai , C. Balaji , M. Sabarinathan , R. Ramesh , M. Navaneethan
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引用次数: 8
摘要
以Ni- mof和GO的质量比(1:0.1,1:0.5,1:1)为条件,通过水热煅烧(400℃,Ar气氛),成功地合成了嵌入在r-GO上的Ni- mof衍生的NiO/Ni纳米颗粒。不同质量比的氧化石墨烯的加入对Ni- mof衍生的NiO/Ni电极材料的电化学性能有较大的影响。质量比为(1:0.5)时,在3 A g−1条件下的比容量最高(649.22 C g−1),在20 A g−1条件下循环5000次后仍保持81.1%的初始容量值。以Ni- mof衍生的NiO/Ni/r-GO复合材料和r-GO为阳极和阴极的组装不对称超级电容器(ASC)也表现出优异的电化学性能。最大能量密度为39.59 W h kg−1,最大功率密度为4.136 kW kg−1,容量保持率为85%。这些结果证实了mof衍生的NiO/Ni/rGO复合材料可以作为一种潜在的超级电容器电极材料。
Ni-MOF derived NiO/Ni/r-GO nanocomposite as a novel electrode material for high-performance asymmetric supercapacitor
Ni-MOF-derived NiO/Ni nanoparticles embedded on r-GO have been successfully synthesized via a hydrothermal method followed by a calcination procedure (400 °C at Ar atmosphere) with different mass ratios of Ni-MOF and GO (1:0.1, 1:0.5, 1:1). The influence of GO addition with various mass ratios could enhance the electrochemical performance of Ni-MOF derived NiO/Ni electrode material. The mass ratio of (1:0.5) demonstrated the highest specific capacity (649.22 C g−1 at 3 A g−1) and maintained 81.1 % of its initial capacity value after 5000 cycles at 20 A g−1. The assembled asymmetric supercapacitors (ASC) with Ni-MOF derived NiO/Ni/r-GO composite and r-GO as the anode and cathode also displayed outstanding electrochemical performance. The value of maximum energy density reached 39.59 W h kg−1 and the maximum power density of 4.136 kW kg−1 with 85 % capacity retention. All these results confirmed that the MOF-derived NiO/Ni/rGO composite can be a potential electrode material for supercapacitors.
期刊介绍:
Journal of energy storage focusses on all aspects of energy storage, in particular systems integration, electric grid integration, modelling and analysis, novel energy storage technologies, sizing and management strategies, business models for operation of storage systems and energy storage developments worldwide.