深共晶溶剂:制备有机硫化合物的替代介质

IF 1.1 Q3 CHEMISTRY, MULTIDISCIPLINARY
Daniela Hartwig, J. Nascimento, Luana Bettanin, Thalita B. Aquino, R. Jacob, E. Lenardão
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引用次数: 2

摘要

深共晶溶剂(DES)作为一种“绿色溶剂”已被广泛用于替代挥发性有机化合物(VOCs)和传统离子液体(ILs)。近年来,DES因其成本低、制备方便、高粘度、低蒸气压、低挥发性、高热稳定性、可生物降解性和无毒性等优异性能而受到广泛关注。由于有机硫化合物在有机反应中作为合成中间体的适用性以及它们在制药和农化工业中的高度重要性,人们对其他类化合物越来越感兴趣。综述了近年来以DES为替代溶剂制备有机硫化合物的研究进展,重点介绍了几种有机反应,包括芳香取代反应(SNAr)、缩合反应、环缩合反应、环化反应、开环反应、硫-迈克尔加成反应、一锅反应和杂环脱水反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Deep Eutectic Solvents: An Alternative Medium for the Preparation of Organosulfur Compounds
Deep Eutectic Solvent (DES) as a “green solvent” has been used as an alternative to replace Volatile Organic Compounds (VOCs) and traditional Ionic Liquids (ILs). In recent years, DES has gained much attention due to its excellent properties such as low cost, easy preparation, high viscosity, low vapor pressure, low volatility, high thermal stability, biodegradability and non-toxicity, among others. Other classes of compounds with increased interest are organosulfur compounds due to their applicability as synthetic intermediates in organic reactions and their high importance in pharmaceutical and agrochemical industries. This review describes the recent advances in the preparation of organosulfur compounds using DES as an alternative solvent, focusing on several types of organic reactions, including aromatic substitution reactions (SNAr), condensation, cyclocondensation, cyclization, ring-opening, thia-Michael addition, one-pot reactions and heterocyclodehydrations.
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来源期刊
Current Green Chemistry
Current Green Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
4.30
自引率
13.60%
发文量
6
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