{"title":"不同种类芳烃的配体活化C-H硼化反应","authors":"Md Emdadul Hoque , Sayan Dey , Mirja Md Mahamudul Hassan , Jagriti Chaturvedi , Saikat Guria , Jaitri Das , Brindaban Roy , Buddhadeb Chattopadhyay","doi":"10.1016/j.tchem.2022.100028","DOIUrl":null,"url":null,"abstract":"<div><p>Here we report a new 6,6′-bipyridine based ligand framework for the iridium-catalysed regioselective ortho borylation of diverse classes of arenes containing different functional groups. Moreover the developed method is highly selective for the directed C(sp (Altus and Love, 2021) [3]-H borylation of the 2-pyridyl amines as well as benzyl and homobenzyl amides directed by pyridine group and amide directed borylation of N-adjacent C–H bond of amides.</p></div>","PeriodicalId":74918,"journal":{"name":"Tetrahedron chem","volume":"3 ","pages":"Article 100028"},"PeriodicalIF":0.0000,"publicationDate":"2022-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666951X22000249/pdfft?md5=8c3b39ad17b803a63b9425471c7d1b9b&pid=1-s2.0-S2666951X22000249-main.pdf","citationCount":"1","resultStr":"{\"title\":\"Ligand-enabled C–H borylation of diverse classes of arenes\",\"authors\":\"Md Emdadul Hoque , Sayan Dey , Mirja Md Mahamudul Hassan , Jagriti Chaturvedi , Saikat Guria , Jaitri Das , Brindaban Roy , Buddhadeb Chattopadhyay\",\"doi\":\"10.1016/j.tchem.2022.100028\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Here we report a new 6,6′-bipyridine based ligand framework for the iridium-catalysed regioselective ortho borylation of diverse classes of arenes containing different functional groups. Moreover the developed method is highly selective for the directed C(sp (Altus and Love, 2021) [3]-H borylation of the 2-pyridyl amines as well as benzyl and homobenzyl amides directed by pyridine group and amide directed borylation of N-adjacent C–H bond of amides.</p></div>\",\"PeriodicalId\":74918,\"journal\":{\"name\":\"Tetrahedron chem\",\"volume\":\"3 \",\"pages\":\"Article 100028\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2666951X22000249/pdfft?md5=8c3b39ad17b803a63b9425471c7d1b9b&pid=1-s2.0-S2666951X22000249-main.pdf\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Tetrahedron chem\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2666951X22000249\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Tetrahedron chem","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666951X22000249","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
摘要
本文报道了一种新的6,6 ' -联吡啶配体框架，用于铱催化含有不同官能团的不同类别芳烃的区域选择性邻位硼化。此外，所开发的方法对2-吡啶基胺的定向C(sp) (Altus and Love, 2021) [3]-H硼化，以及吡啶基导向的苄基和均苯基酰胺和酰胺导向的n邻C -H键硼化具有高度选择性。
Ligand-enabled C–H borylation of diverse classes of arenes
Here we report a new 6,6′-bipyridine based ligand framework for the iridium-catalysed regioselective ortho borylation of diverse classes of arenes containing different functional groups. Moreover the developed method is highly selective for the directed C(sp (Altus and Love, 2021) [3]-H borylation of the 2-pyridyl amines as well as benzyl and homobenzyl amides directed by pyridine group and amide directed borylation of N-adjacent C–H bond of amides.
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