具有外围甲基（3,5-二溴苯基甲基）氨基的卟啉镁的合成和光学性能

IF 1.3 3区化学 Q3 CHEMISTRY, ORGANIC

Heterocyclic Communications Pub Date : 2019-01-01 DOI:10.1515/hc-2019-0001

E. Wieczorek, Jaroslaw Piskorz, L. Popenda, S. Jurga, J. Mielcarek, T. Gośliński

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引用次数: 4

摘要

摘要以市售的二氨基丙烯腈为原料，采用多步反应合成了具有外周甲基（3,5-二溴苯基甲基）胺基的新型卟啉镁（II）。使用紫外-可见光谱、红外光谱、质谱和各种核磁共振技术对所有中间体和最终的大环进行了表征。评价了大环在N，N-二甲基甲酰胺、二甲基亚砜和二氯甲烷中的吸收和发射性能。通过评估大环在二甲基亚砜和N，N-二甲基甲酰胺中产生单线态氧的能力来评估潜在的光敏活性。

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Magnesium porphyrazine with peripheral methyl (3,5-dibromophenylmethyl)amino groups – synthesis and optical properties

Abstract Novel magnesium(II) porphyrazine with peripheral methyl(3,5-dibromophenylmethyl)amine groups was synthesized in a multi-step procedure starting from commercially available diaminomaleonitrile. All intermediates and the final macrocycle were characterized using UV–Vis, FT-IR, MS and various NMR techniques. The absorption and emission properties of the macrocycle were evaluated in N,N-dimethylformamide, dimethyl sulfoxide, and dichloromethane. The potential photosensitizing activity was evaluated by assessing the ability of the macrocycle to generate singlet oxygen in dimethyl sulfoxide and N,N-dimethylformamide.

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来源期刊

Heterocyclic Communications 化学-有机化学

CiteScore

3.80

自引率

4.30%

发文量

审稿时长

1.4 months

期刊介绍： Heterocyclic Communications (HC) is a bimonthly, peer-reviewed journal publishing preliminary communications, research articles, and reviews on significant developments in all phases of heterocyclic chemistry, including general synthesis, natural products, computational analysis, considerable biological activity and inorganic ring systems. Clear presentation of experimental and computational data is strongly emphasized. Heterocyclic chemistry is a rapidly growing field. By some estimates original research papers in heterocyclic chemistry have increased to more than 60% of the current organic chemistry literature published. This explosive growth is even greater when considering heterocyclic research published in materials science, physical, biophysical, analytical, bioorganic, pharmaceutical, medicinal and natural products journals. There is a need, therefore, for a journal dedicated explicitly to heterocyclic chemistry and the properties of heterocyclic compounds.