核电站电缆材料老化模拟方法的问题

IF 1.2 4区 工程技术 Q4 POLYMER SCIENCE
K. Gillen, M. Celina
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引用次数: 0

摘要

在过去的20年里,国际电工委员会和国际原子能机构发布了几份技术文件,描述了在核电站中对电缆材料进行加速辐射加温度老化的推荐方法。这些方法包括幂律方法、时间依赖模型、剂量等效损伤方法和简化方法。由于老化条件转变辐射-温度空间时会发生预期和观察到的化学变化,我们强调了时间相关和简化方法的问题,因为它们没有模拟环境条件下发生的化学。DED方法和最近的一项修改,即匹配加速条件方法,可以处理许多重要电缆材料的化学变化,从而提供更可靠的加速模拟。然后简要介绍了幂律方法存在的问题。还讨论了在试图模拟显示反向温度效应的半晶体电缆材料的老化时出现的重要问题。对于这些材料,在发生典型环境老化条件的温度区域,随着老化温度降至~60°C以下,辐射下的降解率可能会增加。提出了处理这类材料的可能办法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
ISSUES WITH APPROACHES FOR SIMULATING AGING OF NUCLEAR POWER PLANT CABLE MATERIALS
Over the past 20 y, the International Electrotechnical Commission and the International Atomic Energy Agency have published several Technical Documents describing recommended methods for carrying out accelerated radiation plus temperature aging of cable materials in nuclear power plants. These methods include the power law method, the time-dependent model, the dose to equivalent damage approach, and the simplified method approach. Because of the expected and observed changes in chemistry that occur as aging conditions transition radiation–temperature space, we highlight issues with the time-dependent and simplified method approaches by showing that they do not simulate the chemistry occurring under ambient conditions. The DED approach and a recent modification, the Matched Accelerated Conditions approach, can handle the changes in chemistry for many important cable materials and therefore offer more confident accelerated simulations. Problems with the power law method are then briefly described. Also discussed are the significant issues that occur when trying to simulate the aging of semicrystalline cable materials that show inverse-temperature effects. For these materials, degradation rates under radiation can increase as the aging temperature drops below ∼60 °C, in temperature regions where typical ambient aging conditions occur. A possible approach for dealing with such materials is suggested.
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来源期刊
Rubber Chemistry and Technology
Rubber Chemistry and Technology 工程技术-高分子科学
CiteScore
3.50
自引率
20.00%
发文量
21
审稿时长
3.6 months
期刊介绍: The scope of RC&T covers: -Chemistry and Properties- Mechanics- Materials Science- Nanocomposites- Biotechnology- Rubber Recycling- Green Technology- Characterization and Simulation. Published continuously since 1928, the journal provides the deepest archive of published research in the field. Rubber Chemistry & Technology is read by scientists and engineers in academia, industry and government.
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