层状双氢氧化物作为目标离子结构的独特产物,用于能源、化学、食品、化妆品、医学和生态应用。

IF 7 2区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Dr. Vadym Kovalenko, Dr. Valerii Kotok, Dr. Bohdan Murashevych
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引用次数: 0

摘要

层状双氢氧化物(LDH)是M-主体(M2+)氢氧化物的α-改性,其中部分M-主体阳离子被M-客体阳离子(M3+或M4+)取代。出现的过量正电荷通过阴离子嵌入层间空间来补偿,层间空间也包含水分子。LDH具有阴离子交换性质。通过结合三种成分(M-主体、M-客体阳离子、嵌入阴离子)对LDHs进行有针对性的离子设计,可以产生非常广泛的高效电化学、电催化、电致变色物质、催化剂、离子交换剂、吸附剂、色素、药理学药物、食品和化妆品添加剂。在这篇综述中,从特定应用物质的靶向离子设计的角度考虑了LDHs的结构和应用领域。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Layered Double Hydroxides as the Unique Product of Target Ionic Construction for Energy, Chemical, Foods, Cosmetics, Medicine and Ecology Applications

Layered Double Hydroxides as the Unique Product of Target Ionic Construction for Energy, Chemical, Foods, Cosmetics, Medicine and Ecology Applications

Layered Double Hydroxides as the Unique Product of Target Ionic Construction for Energy, Chemical, Foods, Cosmetics, Medicine and Ecology Applications

Layered Double Hydroxide (LDH) is an α-modification of the M-host (M2+) hydroxide, in which some part of the M-host cations is replaced by M-guest cations (M3+ or M4+). The emerging excess positive charge is compensated by the intercalation of anions into the interlayer space, which also contains water molecules. LDHs exhibit anion exchange properties. Targeted ionic design of LDHs via combining three components (M-host, M-guest cations, intercalated anions) allows the creation of a very wide range of highly efficient electrochemical, electrocatalytic, electrochromic substances, catalysts, ion exchangers, sorbents, color pigments, pharmacological drugs, food, and cosmetic additives. In this review, the structure and areas of application of LDHs are considered from the perspective of the targeted ionic design of a substance for a specific application.

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来源期刊
Chemical record
Chemical record 化学-化学综合
CiteScore
11.00
自引率
3.00%
发文量
188
审稿时长
>12 weeks
期刊介绍: The Chemical Record (TCR) is a "highlights" journal publishing timely and critical overviews of new developments at the cutting edge of chemistry of interest to a wide audience of chemists (2013 journal impact factor: 5.577). The scope of published reviews includes all areas related to physical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, polymer chemistry, materials chemistry, bioorganic chemistry, biochemistry, biotechnology and medicinal chemistry as well as interdisciplinary fields. TCR provides carefully selected highlight papers by leading researchers that introduce the author''s own experimental and theoretical results in a framework designed to establish perspectives with earlier and contemporary work and provide a critical review of the present state of the subject. The articles are intended to present concise evaluations of current trends in chemistry research to help chemists gain useful insights into fields outside their specialization and provide experts with summaries of recent key developments.
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