金碳配合物及其以外:金(I)-碳配位化学的新途径

IF 2.2 4区工程技术 Q2 Chemistry

Gold Bulletin Pub Date : 2022-01-03 DOI:10.1007/s13404-021-00298-1

Florian F. Mulks

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引用次数: 1

摘要

研究了碳金(I)配合物中不同的配位模式，以金(I)为重点。介绍了金卡宾配合物的出现及其在学界的重要讨论，并概述了它们的键合原理和合成方法。综述了最近合成和分离的几种有趣的、有时反应性很强的金碳配位配合物，并对其潜在的应用前景进行了评述。这包括偏二烯和更高的累积二烯配合物、含金取代基的游离碳烯、碳二烯配合物和非fischer /Schrock倍半碳烯配合物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Gold carbene complexes and beyond: new avenues in gold(I)-carbon coordination chemistry

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Gold carbene complexes and beyond: new avenues in gold(I)-carbon coordination chemistry

The different coordination modes in carbon-gold(I) complexes are spotlighted with a focus on gold(I). The emergence of gold carbene complexes and their critical discussion in the community is presented, and an overview of their bonding fundamentals and synthetic procedures is given. Several intriguing and sometimes highly reactive gold-carbon coordination complexes that were recently synthesised and isolated are reviewed and a critical outlook into their potential applications is provided. This includes vinylidene and higher cumulenylidene complexes, free carbenes with gold substituents, carbodicarbene complexes, and non-Fischer/Schrock sesquicarbene complexes.

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来源期刊

Gold Bulletin 工程技术-材料科学：综合

CiteScore

3.30

自引率

4.50%

发文量

审稿时长

3 months

期刊介绍： Gold Bulletin is the premier international peer reviewed journal on the latest science, technology and applications of gold. It includes papers on the latest research advances, state-of-the-art reviews, conference reports, book reviews and highlights of patents and scientific literature. Gold Bulletin does not publish manuscripts covering the snthesis of Gold nanoparticles in the presence of plant extracts or other nature-derived extracts. Gold Bulletin has been published over 40 years as a multidisciplinary journal read by chemists, physicists, engineers, metallurgists, materials scientists, biotechnologists, surface scientists, and nanotechnologists amongst others, both within industry and academia. Gold Bulletin is published in Association with the World Gold Council.