A New Band System of the Dicarbon Molecule in the Vacuum Ultraviolet Region

As one of the most abundant molecules in the universe, the long history of spectroscopic studies of the dicarbon molecule, C₂, reaches back two centuries. While many electronic band systems with upper states below the lowest dissociation threshold have been well characterized, much less is known about transitions to higher-lying states. Here, we report the observation of a new band system of C₂ from the lowest triplet state a³Π_u through a resonance-enhanced multiphoton ionization scheme. The upper state is identified as 1³Σ_g⁺, which is determined to be 61539.0 cm^–1 (7.630 eV) above ground state X¹Σ_g⁺. The spectroscopic parameters determined for the 1³Σ_g⁺ state are in excellent agreement with those predicted by the high-level ab initio calculations. This study paves the way for systematic investigations of the photoabsorption and photodissociation of C₂ in the vacuum ultraviolet region, which has important applications in the field of astrochemistry.