Fe3O4和MnxOy两种磁性子系统新型玻璃材料的合成与研究

IF 0.8 4区 材料科学 Q4 MATERIALS SCIENCE, CERAMICS
O. A. Pshenko, T. V. Antropova, L. N. Kurilenko, I. G. Polyakova, I. N. Anfimova
{"title":"Fe3O4和MnxOy两种磁性子系统新型玻璃材料的合成与研究","authors":"O. A. Pshenko,&nbsp;T. V. Antropova,&nbsp;L. N. Kurilenko,&nbsp;I. G. Polyakova,&nbsp;I. N. Anfimova","doi":"10.1134/S1087659623600114","DOIUrl":null,"url":null,"abstract":"<p>New vitreous composite materials (CMs) with two magnetic subsystems are synthesized by impregnation magnetite-containing matrices from iron-containing nanoporous glasses in aqueous MnCl<sub>2</sub> and H<sub>2</sub>C<sub>2</sub>O<sub>4</sub> solutions and the subsequent formation of manganese oxides Mn<sub><i>x</i></sub>O<sub><i>y</i></sub> (<i>x</i> = 1, 2, 3; <i>y</i> = 1, 2, 3, 4) inside the pore space of the matrices as a result of thermolysis of the reaction product of the dopants (MnC<sub>2</sub>O<sub>4</sub>). The chemical (elemental) and phase compositions, the valence-coordination state of iron and manganese, and the characteristics of the magnetic state of the synthesized CMs are studied and compared with the characteristics of nanoporous matrices.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":null,"pages":null},"PeriodicalIF":0.8000,"publicationDate":"2023-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Investigation of New Vitreous Materials with Two Magnetic Subsystems (Fe3O4 and MnxOy)\",\"authors\":\"O. A. Pshenko,&nbsp;T. V. Antropova,&nbsp;L. N. Kurilenko,&nbsp;I. G. Polyakova,&nbsp;I. N. Anfimova\",\"doi\":\"10.1134/S1087659623600114\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>New vitreous composite materials (CMs) with two magnetic subsystems are synthesized by impregnation magnetite-containing matrices from iron-containing nanoporous glasses in aqueous MnCl<sub>2</sub> and H<sub>2</sub>C<sub>2</sub>O<sub>4</sub> solutions and the subsequent formation of manganese oxides Mn<sub><i>x</i></sub>O<sub><i>y</i></sub> (<i>x</i> = 1, 2, 3; <i>y</i> = 1, 2, 3, 4) inside the pore space of the matrices as a result of thermolysis of the reaction product of the dopants (MnC<sub>2</sub>O<sub>4</sub>). The chemical (elemental) and phase compositions, the valence-coordination state of iron and manganese, and the characteristics of the magnetic state of the synthesized CMs are studied and compared with the characteristics of nanoporous matrices.</p>\",\"PeriodicalId\":580,\"journal\":{\"name\":\"Glass Physics and Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2023-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Glass Physics and Chemistry\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S1087659623600114\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Glass Physics and Chemistry","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S1087659623600114","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0

摘要

以含铁纳米多孔玻璃为原料,在MnCl2和H2C2O4水溶液中浸渍含磁铁矿基质,生成锰氧化物MnxOy (x = 1,2,3;y = 1,2,3,4),这是由于掺杂剂(MnC2O4)的反应产物热裂解的结果。研究了合成的CMs的化学(元素)和物相组成、铁和锰的配位态以及磁性态的特征,并与纳米多孔基质的特征进行了比较。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Synthesis and Investigation of New Vitreous Materials with Two Magnetic Subsystems (Fe3O4 and MnxOy)

Synthesis and Investigation of New Vitreous Materials with Two Magnetic Subsystems (Fe3O4 and MnxOy)

New vitreous composite materials (CMs) with two magnetic subsystems are synthesized by impregnation magnetite-containing matrices from iron-containing nanoporous glasses in aqueous MnCl2 and H2C2O4 solutions and the subsequent formation of manganese oxides MnxOy (x = 1, 2, 3; y = 1, 2, 3, 4) inside the pore space of the matrices as a result of thermolysis of the reaction product of the dopants (MnC2O4). The chemical (elemental) and phase compositions, the valence-coordination state of iron and manganese, and the characteristics of the magnetic state of the synthesized CMs are studied and compared with the characteristics of nanoporous matrices.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Glass Physics and Chemistry
Glass Physics and Chemistry 工程技术-材料科学:硅酸盐
CiteScore
1.20
自引率
14.30%
发文量
46
审稿时长
6-12 weeks
期刊介绍: Glass Physics and Chemistry presents results of research on the inorganic and physical chemistry of glass, ceramics, nanoparticles, nanocomposites, and high-temperature oxides and coatings. The journal welcomes manuscripts from all countries in the English or Russian language.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信