用于同时电解-超声-电化学聚合的超声螺旋线圈电化学反应器及其在花粉清洗中的应用。

IF 1.8 4区 化学 Q3 POLYMER SCIENCE
Designed Monomers and Polymers Pub Date : 2021-11-17 eCollection Date: 2021-01-01 DOI:10.1080/15685551.2021.2003557
Kyoka Komaba, Hiromasa Goto
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引用次数: 3

摘要

研究了超声波与电解水相结合的苯胺电化学聚合反应。该方法包括三个过程:1)通过电解阳极一侧的水产生O2微气泡,2)通过超声波机械振动使电极表面的气泡去极化,扩散电解质溶液中的离子,3)通过直流(DC)电化学聚合的进展,产生表面上有细孔的导电聚合物。孔的直径在微米尺度上,与花粉的大小相似。导电聚合物的电子功能与多孔聚合物表面的结合可以作为一种收集灰尘和花粉等过敏原的方法。采用微泡超声电化学法制备多孔聚苯胺,对花粉进行电吸附和解吸。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Ultrasonic helical coil electrochemical reactor for simultaneous electrolysis-sonification-electrochemical polymerization, and applications for pollen cleaning.

Electrochemical polymerization of aniline by a combination of ultrasonic waves and electrolysis of water was performed. This method involves three processes: 1) creation of O2 micro bubbles produced by electrolysis of water on the anode side, 2) depolarization of the bubbles at the electrode surface via mechanical vibration using ultrasonic waves to diffuse ions in the electrolyte solution, and 3) progression of direct current (DC) electrochemical polymerization to yield a conductive polymer with fine pores on the surface. The diameter of the pores is on the micrometer scale and is similar in size to pollens. The combination of the electronic function of the conductive polymer and porous polymer surface can be applied as a method to collect allergens such as dust and flower pollens. Electrical adsorption and desorption of pollen was conducted with the porous polyaniline synthesized using a micro-bubble sonic-electrochemical preparation.

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来源期刊
Designed Monomers and Polymers
Designed Monomers and Polymers 化学-高分子科学
CiteScore
3.30
自引率
0.00%
发文量
28
审稿时长
2.1 months
期刊介绍: Designed Monomers and Polymers ( DMP) publishes prompt peer-reviewed papers and short topical reviews on all areas of macromolecular design and applications. Emphasis is placed on the preparations of new monomers, including characterization and applications. Experiments should be presented in sufficient detail (including specific observations, precautionary notes, use of new materials, techniques, and their possible problems) that they could be reproduced by any researcher wishing to repeat the work. The journal also includes macromolecular design of polymeric materials (such as polymeric biomaterials, biomedical polymers, etc.) with medical applications. DMP provides an interface between organic and polymer chemistries and aims to bridge the gap between monomer synthesis and the design of new polymers. Submssions are invited in the areas including, but not limited to: -macromolecular science, initiators, macroinitiators for macromolecular design -kinetics, mechanism and modelling aspects of polymerization -new methods of synthesis of known monomers -new monomers (must show evidence for polymerization, e.g. polycondensation, sequential combination, oxidative coupling, radiation, plasma polymerization) -functional prepolymers of various architectures such as hyperbranched polymers, telechelic polymers, macromonomers, or dendrimers -new polymeric materials with biomedical applications
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