Electrochemiluminescence Quenching Sensor of a Carboxylic Carbon Nanotubes Modified Glassy Carbon Electrode for Detecting Crystal Violet Based on Nitrogen-doped Graphene Quantum Dots@Peroxydisulfate System

In this work, the electrochemiluminscence system of nitrogen-doped graphene quantum dots (N-GQDs) and K₂S₂O₈ was built for the determination of crystal violet (CV). Meanwhile, a carboxylic carbon nanotubes modified glassy carbon electrode (CCNTs/GCE) was used as an ECL sensor. Thanks to the excellent electron transfer ability and large surface area of CCNTs, the ECL signal of N-GQDs@S₂O₈²⁻ was remarkablely amplified. With the presence of a low concentration of CV, a distinct decrease of the ECL signal was observed due to a quenching effect of CV on the ECL emission. Moreover, the quenched ECL intensity responded linearly to the logarithm of CV concentration within the range of 0.05 - 5 μmol/L, with a LOD of 45 nmol/L (S/N = 3). The proposed ECL system exhibited high sensitivity and specificity to CV, which was successfully applied in the practical detection of CV in real water samples from a local fishpond farm.