Hydrogen peroxide emissions from surface cleaning in a single-family residence†

High levels of reactive chemicals may be emitted to the indoor air during household surface cleaning, leading to poorer air quality and potential health hazards. Hydrogen peroxide (H₂O₂)-based cleaners have gained popularity in recent years, especially in times of COVID-19. Still, little is known regarding the effects of H₂O₂ cleaning on indoor air composition. In this work we monitored time-resolved H₂O₂ concentrations during a cleaning campaign in an occupied single-family residence using a cavity ring-down spectroscopy (CRDS) H₂O₂ analyzer. During the cleaning experiments, we investigated how unconstrained (i.e., “real-life”) surface cleaning with a hydrogen peroxide solution influenced the indoor air quality of the house, and performed controlled experiments to investigate factors that could influence H₂O₂ levels including surface area and surface material, ventilation, and dwell time of the cleaning solution. Mean peak H₂O₂ concentrations observed following all surface cleaning events were 135 ppbv. The factors with the greatest effect on H₂O₂ levels were distance of the cleaned surface from the detector inlet, type of surface cleaned, and solution dwell time.