十钨酸盐光- hat /镍协同催化下烃类的直接酰化和炔化反应

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2022-01-01 DOI:10.1039/d2cc04408k

Wenfeng Liu , Yang Ke , Chuhan Liu , Wangqing Kong

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引用次数: 0

摘要

在此，我们描述了一种通过协同十钨酸盐光催化和镍催化对饱和烃的C(sp3) -H键进行直接和选择性的酰化和烷基化的方案。该方法使用便宜且易于合成的TBADT作为HAT光催化剂，具有良好的位点选择性。从丰富的烃类原料中可以高效地合成各种高价值的酮类、酰胺类、酯类和炔类。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Direct acylation and alkynylation of hydrocarbons via synergistic decatungstate photo-HAT/nickel catalysis†

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Direct acylation and alkynylation of hydrocarbons via synergistic decatungstate photo-HAT/nickel catalysis†

Herein, we describe a protocol for the direct and selective acylation and alkynylation of the C(sp³)–H bonds of saturated hydrocarbons by synergistic decatungstate photo-HAT and nickel catalysis. This method, using cheap and easy-to-synthesize TBADT as a HAT photocatalyst, exhibits excellent site selectivity. A wide variety of high-value ketones, amides, esters, and diverse alkynes can be efficiently constructed from abundant hydrocarbon feedstocks.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.