Rui Du , Xiaoxia Feng , Pu Wang , Ruiqiang Yang , Gang Li , Jianjie Fu , Yong Liang , Ting Ruan , Guibin Jiang
{"title":"利用粪便和污水标记物评估湖泊沉积物中合成添加剂污染物的发生和来源","authors":"Rui Du , Xiaoxia Feng , Pu Wang , Ruiqiang Yang , Gang Li , Jianjie Fu , Yong Liang , Ting Ruan , Guibin Jiang","doi":"10.1016/j.envpol.2023.121942","DOIUrl":null,"url":null,"abstract":"<div><p>Benzotriazole ultraviolet stabilizers (BZT-UVs), substituted diphenylamine antioxidants (S-DPAs), and synthetic phenolic antioxidants (SPAs) are three types of synthetic additive pollutants that are received increasing attention in the recent decade. In this study, a total of twenty-seven target analytes were measured in sediment cores and surface sediments collected from a lake with long sedimentary history. All target analytes were detected in the sediment samples, and mean values of the total ∑BZT-UVs, ∑S-DPAs and ∑SPAs concentrations were 220 ± 552 ng/g dry weight (d.w.), 20.8 ± 27.9 ng/g d. w., and 95.8 ± 146 ng/g d. w., respectively. Based on the dating results of two sediment cores, the total concentrations of BZT-UVs, S-DPA, and SPAs showed a fluctuating but overall increasing trend over time, which intuitively reflects the change of historical emissions. Meanwhile, fecal and sewage markers (i.e., sterols and pharmaceuticals, respectively) were jointly used to trace the probable sources of these pollutants. Results from the correlation and clustering analyses suggest that unregular fecal discharges and point-source domestic sewage need to be considered if pollution in the investigated area is to be controlled. To our knowledge, this study is the initial attempt to reveal the temporal variations of these synthetic additive pollutants in an aquatic environment in China and to demonstrate the feasibility of using markers to trace the sources of emerging pollutant analogues.</p></div>","PeriodicalId":311,"journal":{"name":"Environmental Pollution","volume":"331 ","pages":"Article 121942"},"PeriodicalIF":7.6000,"publicationDate":"2023-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Assessing the occurrence and sources of synthetic additive pollutants in lake sediments using fecal and sewage markers\",\"authors\":\"Rui Du , Xiaoxia Feng , Pu Wang , Ruiqiang Yang , Gang Li , Jianjie Fu , Yong Liang , Ting Ruan , Guibin Jiang\",\"doi\":\"10.1016/j.envpol.2023.121942\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Benzotriazole ultraviolet stabilizers (BZT-UVs), substituted diphenylamine antioxidants (S-DPAs), and synthetic phenolic antioxidants (SPAs) are three types of synthetic additive pollutants that are received increasing attention in the recent decade. In this study, a total of twenty-seven target analytes were measured in sediment cores and surface sediments collected from a lake with long sedimentary history. All target analytes were detected in the sediment samples, and mean values of the total ∑BZT-UVs, ∑S-DPAs and ∑SPAs concentrations were 220 ± 552 ng/g dry weight (d.w.), 20.8 ± 27.9 ng/g d. w., and 95.8 ± 146 ng/g d. w., respectively. Based on the dating results of two sediment cores, the total concentrations of BZT-UVs, S-DPA, and SPAs showed a fluctuating but overall increasing trend over time, which intuitively reflects the change of historical emissions. Meanwhile, fecal and sewage markers (i.e., sterols and pharmaceuticals, respectively) were jointly used to trace the probable sources of these pollutants. Results from the correlation and clustering analyses suggest that unregular fecal discharges and point-source domestic sewage need to be considered if pollution in the investigated area is to be controlled. To our knowledge, this study is the initial attempt to reveal the temporal variations of these synthetic additive pollutants in an aquatic environment in China and to demonstrate the feasibility of using markers to trace the sources of emerging pollutant analogues.</p></div>\",\"PeriodicalId\":311,\"journal\":{\"name\":\"Environmental Pollution\",\"volume\":\"331 \",\"pages\":\"Article 121942\"},\"PeriodicalIF\":7.6000,\"publicationDate\":\"2023-08-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Environmental Pollution\",\"FirstCategoryId\":\"93\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0269749123009442\",\"RegionNum\":2,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENVIRONMENTAL SCIENCES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Pollution","FirstCategoryId":"93","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0269749123009442","RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
Assessing the occurrence and sources of synthetic additive pollutants in lake sediments using fecal and sewage markers
Benzotriazole ultraviolet stabilizers (BZT-UVs), substituted diphenylamine antioxidants (S-DPAs), and synthetic phenolic antioxidants (SPAs) are three types of synthetic additive pollutants that are received increasing attention in the recent decade. In this study, a total of twenty-seven target analytes were measured in sediment cores and surface sediments collected from a lake with long sedimentary history. All target analytes were detected in the sediment samples, and mean values of the total ∑BZT-UVs, ∑S-DPAs and ∑SPAs concentrations were 220 ± 552 ng/g dry weight (d.w.), 20.8 ± 27.9 ng/g d. w., and 95.8 ± 146 ng/g d. w., respectively. Based on the dating results of two sediment cores, the total concentrations of BZT-UVs, S-DPA, and SPAs showed a fluctuating but overall increasing trend over time, which intuitively reflects the change of historical emissions. Meanwhile, fecal and sewage markers (i.e., sterols and pharmaceuticals, respectively) were jointly used to trace the probable sources of these pollutants. Results from the correlation and clustering analyses suggest that unregular fecal discharges and point-source domestic sewage need to be considered if pollution in the investigated area is to be controlled. To our knowledge, this study is the initial attempt to reveal the temporal variations of these synthetic additive pollutants in an aquatic environment in China and to demonstrate the feasibility of using markers to trace the sources of emerging pollutant analogues.
期刊介绍:
Environmental Pollution is an international peer-reviewed journal that publishes high-quality research papers and review articles covering all aspects of environmental pollution and its impacts on ecosystems and human health.
Subject areas include, but are not limited to:
• Sources and occurrences of pollutants that are clearly defined and measured in environmental compartments, food and food-related items, and human bodies;
• Interlinks between contaminant exposure and biological, ecological, and human health effects, including those of climate change;
• Contaminants of emerging concerns (including but not limited to antibiotic resistant microorganisms or genes, microplastics/nanoplastics, electronic wastes, light, and noise) and/or their biological, ecological, or human health effects;
• Laboratory and field studies on the remediation/mitigation of environmental pollution via new techniques and with clear links to biological, ecological, or human health effects;
• Modeling of pollution processes, patterns, or trends that is of clear environmental and/or human health interest;
• New techniques that measure and examine environmental occurrences, transport, behavior, and effects of pollutants within the environment or the laboratory, provided that they can be clearly used to address problems within regional or global environmental compartments.