通过基于同步加速器的核能级光电子能谱在表面探索二维材料

IF 8.2 1区 化学 Q1 CHEMISTRY, PHYSICAL
Luca Bignardi , Paolo Lacovig , Rosanna Larciprete , Dario Alfè , Silvano Lizzit , Alessandro Baraldi
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引用次数: 1

摘要

在过去的几年里,人们对理解和控制二维材料(2dm)的特性产生了浓厚的兴趣,这促成了涉及凝聚态物理和材料科学的重要的多学科研究。虽然2dm已经用一系列不同的实验和理论方法进行了研究,但使用基于表面科学的技术进行的实验对于阐明该材料家族的许多特性至关重要。特别是,基于同步加速器的x射线光电子能谱(XPS)在研究2dm的特性方面发挥了核心作用,为这些材料提供了深入和精确的表征,并有助于阐明与它们相关的许多难以捉摸和复杂的方面。例如,XPS对于理解几种2dm在表面的生长机制和确定控制它的参数至关重要。此外,该技术的化学敏感性对于获得功能化2dm的知识以及在几种模型化学反应中测试其行为至关重要。迄今在这一领域所取得的成就已达到成熟的程度,因此有必要对其里程碑进行回顾。在这篇综述中,我们将展示相关的2dm研究实例,其中基于同步加速器的XPS,结合其他技术和电子结构和生长机制的最新理论建模,对于揭示与表面2dm合成和性质相关的许多方面至关重要。本文强调的结果和实现这些结果所遵循的方法将作为研究人员测试和比较其研究成果的指导,并促进进一步的研究,以扩展广泛而通用的2dm家族的知识。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Exploring 2D materials at surfaces through synchrotron-based core-level photoelectron spectroscopy

The interest in understanding and controlling the properties of two-dimensional materials (2DMs) has fostered in the last years a significant and multidisciplinary research effort involving condensed matter physics and materials science. Although 2DMs have been investigated with a wide set of different experimental and theoretical methodologies, experiments carried out with surface-science based techniques were essential to elucidate many aspects of the properties of this family of materials. In particular, synchrotron-based X-ray photoelectron spectroscopy (XPS) has been playing a central role in casting light on the properties of 2DMs, providing an in-depth and precise characterization of these materials and helping to elucidate many elusive and intricate aspects related to them. XPS was crucial, for example, in understanding the mechanism of growth of several 2DMs at surfaces and in identifying the parameters governing it. Moreover, the chemical sensitivity of this technique is crucial in obtaining knowledge about functionalized 2DMs and in testing their behavior in several model chemical reactions. The achievements accomplished so far in this field have reached a maturity point for which a recap of the milestones is desirable. In this review, we will showcase relevant examples of studies on 2DMs for which synchrotron-based XPS, in combination with other techniques and state-of-the-art theoretical modeling of the electronic structure and of the growth mechanisms, was essential to unravel many aspects connected to the synthesis and properties of 2DMs at surfaces. The results highlighted herein and the methodologies followed to achieve them will serve as a guidance to researchers in testing and comparing their research outcomes and in stimulating further investigations to expand the knowledge of the broad and versatile 2DMs family.

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来源期刊
Surface Science Reports
Surface Science Reports 化学-物理:凝聚态物理
CiteScore
15.90
自引率
2.00%
发文量
9
审稿时长
178 days
期刊介绍: Surface Science Reports is a journal that specializes in invited review papers on experimental and theoretical studies in the physics, chemistry, and pioneering applications of surfaces, interfaces, and nanostructures. The topics covered in the journal aim to contribute to a better understanding of the fundamental phenomena that occur on surfaces and interfaces, as well as the application of this knowledge to the development of materials, processes, and devices. In this journal, the term "surfaces" encompasses all interfaces between solids, liquids, polymers, biomaterials, nanostructures, soft matter, gases, and vacuum. Additionally, the journal includes reviews of experimental techniques and methods used to characterize surfaces and surface processes, such as those based on the interactions of photons, electrons, and ions with surfaces.
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