富勒烯C60和C70在高溶解度有机溶剂中的改进分光光度分析

IF 1.8 4区 化学 Q3 CHEMISTRY, ANALYTICAL
Alexander Törpe, Daniel J. Belton
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引用次数: 13

摘要

富勒烯是最近发现的许多具有独特和多功能性质的碳同素异形体之一。对这些材料的分析是非常重要和令人感兴趣的。我们提供了以前未报道的C60和C70富勒烯在高溶解度溶剂中的光谱数据,包括误差范围,以便对这些材料进行可靠的比色分析。比尔-朗伯-布格定律被发现在所有波长下都是有效的。测量数据具有高度可重复性,并产生了C60和C70在邻二甲苯和邻二氯苯中的高精度摩尔吸收系数,这两种富勒烯对这些富勒烯都表现出高溶解度,并提供了提高提取效率的前景。C60/C70混合物分析的光度法用标准混合物进行了验证,随后通过使用幂律拟合校正光散射,对真实样品进行了改进。该方法成功地应用于富勒烯烟灰中C60/C70混合物的分析。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Improved Spectrophotometric Analysis of Fullerenes C60 and C70 in High-solubility Organic Solvents

Fullerenes are among a number of recently discovered carbon allotropes that exhibit unique and versatile properties. The analysis of these materials is of great importance and interest. We present previously unreported spectroscopic data for C60 and C70 fullerenes in high-solubility solvents, including error bounds, so as to allow reliable colorimetric analysis of these materials. The Beer-Lambert-Bouguer law is found to be valid at all wavelengths. The measured data were highly reproducible, and yielded high-precision molar absorbance coefficients for C60 and C70 in o-xylene and o-dichlorobenzene, which both exhibit a high solubility for these fullerenes, and offer the prospect of improved extraction efficiency. A photometric method for a C60/C70 mixture analysis was validated with standard mixtures, and subsequently improved for real samples by correcting for light scattering, using a power-law fit. The method was successfully applied to the analysis of C60/C70 mixtures extracted from fullerene soot.

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来源期刊
Analytical Sciences
Analytical Sciences 化学-分析化学
CiteScore
2.90
自引率
18.80%
发文量
232
审稿时长
1 months
期刊介绍: Analytical Sciences is an international journal published monthly by The Japan Society for Analytical Chemistry. The journal publishes papers on all aspects of the theory and practice of analytical sciences, including fundamental and applied, inorganic and organic, wet chemical and instrumental methods. This publication is supported in part by the Grant-in-Aid for Publication of Scientific Research Result of the Japanese Ministry of Education, Culture, Sports, Science and Technology.
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