光催化和电催化CO2还原的mof基材料

IF 22.2 Q1 CHEMISTRY, MULTIDISCIPLINARY
Xiaofang Li, Qi-Long Zhu
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引用次数: 173

摘要

金属有机骨架(MOFs)在光催化和电催化CO2还原成高附加值化学品方面受到了广泛的关注。在这篇综述中,我们特别关注mof基材料的活性位点,分别实现可见光吸收和光催化CO2还原的有效电荷分离,以及电催化CO2还原的导电性。首先介绍了mof基材料催化CO2还原的独特特性。随后,通过对mof基材料的类型和活性位点的来源进行分类,综述了mof基材料催化CO2还原的最新进展和发展。活性金属节点/簇和有机配体可以组装在原始mof中用于催化CO2还原。多种活性物质与MOF结合形成MOF复合材料,用于催化CO2还原。此外,MOF及其复合材料作为模板和/或前驱体被广泛用于合成MOF衍生物,用于催化CO2还原。最后,提出了mof基材料未来发展面临的挑战和前景。本文对mof基材料在光催化和电催化CO2还原中的应用进行了总结,旨在启发这一研究领域进一步的思路和探索。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
MOF-based materials for photo- and electrocatalytic CO2 reduction

Metal–organic frameworks (MOFs) have attracted much attention in photo- and electrocatalytic CO2 reduction into value-added chemicals. In this review, we specially focus on the active sites of MOF-based materials to achieve visible-light absorption and efficient charge separation for photocatalytic CO2 reduction, and conductivity for electrocatalytic CO2 reduction, respectively. Firstly, the unique characteristics of MOF-based materials for catalytic CO2 reduction are introduced. Subsequently, an overview on the recent progress and development of MOF-based materials for catalytic CO2 reduction are summarized by categorizing the types of the MOF-based materials and the origin of the active sites. The active metal nodes/clusters and organic ligands can be assembled in pristine MOFs for catalytic CO2 reduction. Diverse active species are also popular to integrate with MOFs to form MOF composites for catalytic CO2 reduction. Besides, MOFs and their composites are intensively explored as templates and/or precursors to synthesize MOF derivatives for catalytic CO2 reduction. Finally, the challenges and perspectives for further development towards MOF-based materials for CO2 reduction are proposed. We have tried our best to summarize the MOF-based materials for photo- and electrocatalytic CO2 reduction, aiming to inspire further ideas and exploration in this research field.

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来源期刊
EnergyChem
EnergyChem Multiple-
CiteScore
40.80
自引率
2.80%
发文量
23
审稿时长
40 days
期刊介绍: EnergyChem, a reputable journal, focuses on publishing high-quality research and review articles within the realm of chemistry, chemical engineering, and materials science with a specific emphasis on energy applications. The priority areas covered by the journal include:Solar energy,Energy harvesting devices,Fuel cells,Hydrogen energy,Bioenergy and biofuels,Batteries,Supercapacitors,Electrocatalysis and photocatalysis,Energy storage and energy conversion,Carbon capture and storage
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