弹性体加速老化及寿命预测研究进展综述

IF 6.3 2区 化学 Q1 POLYMER SCIENCE
Masoud Tayefi , Mostafa Eesaee , Meysam Hassanipour , Said Elkoun , Eric David , Phuong Nguyen-Tri
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引用次数: 1

摘要

无论增强与否,弹性体材料的加速热老化问题都受到了研究人员的广泛关注。这很有趣,因为老化是弹性体的一个经典问题,它会改变弹性体的性能,从而影响它们的使用寿命。然而,弹性体在其运行环境中的老化是非常耗时的。许多关于加速老化的研究都集中在了解暴露在高温下对材料的化学和物理方面的影响。这类弹性体对老化的机械和化学反应与基础橡胶的特性、固化体系、增强剂和添加剂的性质、弹性体和增强剂或/和与基体共混的聚合物之间的界面相互作用以及填料的表面积直接相关。因此,加速老化提供了一种有效的工具,可以减少材料在正常使用条件下达到退化材料性能的时间。它有助于我们了解配方的问题,并知道在不容易检查的应用中使用的弹性体部件的适当时间更换,例如电气工业,石油和天然气工业,海洋工业等中使用的几种弹性体材料。本工作旨在收集和比较过去二十年来在弹性体加速老化方面所做的工作,为今后的工作提供参考。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Recent progress in the accelerated aging and lifetime prediction of elastomers : A review

The accelerated thermal aging of elastomeric compounds, reinforced or not, has received considerable attention from researchers. It is interesting because aging is a classic problem in elastomers that alters their properties and, consequently, their service life. However, the aging of elastomers in their operational environment can be time-consuming. Many studies into accelerated aging have focused on understanding the effect of exposure to elevated temperatures on the chemical and physical aspects of the materials. The mechanical and chemical response of such elastomers to aging is directly related to the features of the base rubber, the curing system, the nature of reinforcement and additives, the interfacial interactions between the elastomer and reinforcements or/and polymer blended with the matrix, and the surface area of the filler. Therefore, accelerated aging provides an effective tool to reduce the time to reach a material with the properties of a degraded material in its normal application condition. It helps us to understand the problem with the formulation and to know the proper time to change the elastomer parts used in applications that is not easy to inspect, such as the several elastomeric materials used in the electrical industries, oil and gas industry industries, marine industries, etc. This work aims to collect and compare the works carried out during the past two decades on the accelerated aging of elastomers to form a reference for future work.

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来源期刊
Polymer Degradation and Stability
Polymer Degradation and Stability 化学-高分子科学
CiteScore
10.10
自引率
10.20%
发文量
325
审稿时长
23 days
期刊介绍: Polymer Degradation and Stability deals with the degradation reactions and their control which are a major preoccupation of practitioners of the many and diverse aspects of modern polymer technology. Deteriorative reactions occur during processing, when polymers are subjected to heat, oxygen and mechanical stress, and during the useful life of the materials when oxygen and sunlight are the most important degradative agencies. In more specialised applications, degradation may be induced by high energy radiation, ozone, atmospheric pollutants, mechanical stress, biological action, hydrolysis and many other influences. The mechanisms of these reactions and stabilisation processes must be understood if the technology and application of polymers are to continue to advance. The reporting of investigations of this kind is therefore a major function of this journal. However there are also new developments in polymer technology in which degradation processes find positive applications. For example, photodegradable plastics are now available, the recycling of polymeric products will become increasingly important, degradation and combustion studies are involved in the definition of the fire hazards which are associated with polymeric materials and the microelectronics industry is vitally dependent upon polymer degradation in the manufacture of its circuitry. Polymer properties may also be improved by processes like curing and grafting, the chemistry of which can be closely related to that which causes physical deterioration in other circumstances.
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