Hao Peng , Man He , Yuming Zhou , Zhaoping Song , Yongjuan Wang , Shuangjiang Feng , Xi Chen , Xian Zhang , Hao Chen
{"title":"低温碳化仿生纤维素纳米纤维/MXene复合膜具有优异的微波吸收性能和可调的吸收带","authors":"Hao Peng , Man He , Yuming Zhou , Zhaoping Song , Yongjuan Wang , Shuangjiang Feng , Xi Chen , Xian Zhang , Hao Chen","doi":"10.1016/j.cej.2021.133269","DOIUrl":null,"url":null,"abstract":"<div><p>2D transition metal carbides and nitrides (MXenes) have gained much interest in microwave absorption. However, the high conductivity of MXenes results in inferior absorption performance. To solve this problem, Cellulose nanofiber (CNF) is compounded with MXenes to build membranes with biomimetic structures. CNF not only contributes to adjusting the electromagentic parameters, but also enhances the microwave attenuation and regulates the absorption band. In this work, nacre-like and loofah-like carbonized CNF/MXenes membranes were successfully prepared. The self-assembly of CNF and MXene avoids the impedance mismatch, and the biomimetic structures enhance conductive loss, polarization loss and multiple reflection. The results show that nacre-like carbonized CNF/MXene membrane (CCM) exhibits absorbing performance with the minimum reflection loss (RL<sub>min</sub>) of −42.2 dB and the Effective absorption band (EAB) of 7.12 GHz. Meanwhile, the absorption peaks are mainly concentrated on X-band. Further, as the morphology changes to porous layers, the RL<sub>min</sub> of loofah-like CCM increases to −63.8 dB, whose EAB is 7.32 GHz at 2.5 mm, and the main absorption peaks shift to Ku-band. Besides, the possible absorption mechanism of biomimetic composite membranes has been expounded. This work provides a versatile strategy for CNF/MXene composite membrane with biomimetic structures on excellent and tunable microwave absorption performance.</p></div>","PeriodicalId":270,"journal":{"name":"Chemical Engineering Journal","volume":"433 ","pages":"Article 133269"},"PeriodicalIF":13.3000,"publicationDate":"2022-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"49","resultStr":"{\"title\":\"Low-temperature carbonized biomimetic cellulose nanofiber/MXene composite membrane with excellent microwave absorption performance and tunable absorption bands\",\"authors\":\"Hao Peng , Man He , Yuming Zhou , Zhaoping Song , Yongjuan Wang , Shuangjiang Feng , Xi Chen , Xian Zhang , Hao Chen\",\"doi\":\"10.1016/j.cej.2021.133269\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>2D transition metal carbides and nitrides (MXenes) have gained much interest in microwave absorption. However, the high conductivity of MXenes results in inferior absorption performance. To solve this problem, Cellulose nanofiber (CNF) is compounded with MXenes to build membranes with biomimetic structures. CNF not only contributes to adjusting the electromagentic parameters, but also enhances the microwave attenuation and regulates the absorption band. In this work, nacre-like and loofah-like carbonized CNF/MXenes membranes were successfully prepared. The self-assembly of CNF and MXene avoids the impedance mismatch, and the biomimetic structures enhance conductive loss, polarization loss and multiple reflection. The results show that nacre-like carbonized CNF/MXene membrane (CCM) exhibits absorbing performance with the minimum reflection loss (RL<sub>min</sub>) of −42.2 dB and the Effective absorption band (EAB) of 7.12 GHz. Meanwhile, the absorption peaks are mainly concentrated on X-band. Further, as the morphology changes to porous layers, the RL<sub>min</sub> of loofah-like CCM increases to −63.8 dB, whose EAB is 7.32 GHz at 2.5 mm, and the main absorption peaks shift to Ku-band. Besides, the possible absorption mechanism of biomimetic composite membranes has been expounded. This work provides a versatile strategy for CNF/MXene composite membrane with biomimetic structures on excellent and tunable microwave absorption performance.</p></div>\",\"PeriodicalId\":270,\"journal\":{\"name\":\"Chemical Engineering Journal\",\"volume\":\"433 \",\"pages\":\"Article 133269\"},\"PeriodicalIF\":13.3000,\"publicationDate\":\"2022-04-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"49\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Engineering Journal\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1385894721048440\",\"RegionNum\":1,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Engineering Journal","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1385894721048440","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
Low-temperature carbonized biomimetic cellulose nanofiber/MXene composite membrane with excellent microwave absorption performance and tunable absorption bands
2D transition metal carbides and nitrides (MXenes) have gained much interest in microwave absorption. However, the high conductivity of MXenes results in inferior absorption performance. To solve this problem, Cellulose nanofiber (CNF) is compounded with MXenes to build membranes with biomimetic structures. CNF not only contributes to adjusting the electromagentic parameters, but also enhances the microwave attenuation and regulates the absorption band. In this work, nacre-like and loofah-like carbonized CNF/MXenes membranes were successfully prepared. The self-assembly of CNF and MXene avoids the impedance mismatch, and the biomimetic structures enhance conductive loss, polarization loss and multiple reflection. The results show that nacre-like carbonized CNF/MXene membrane (CCM) exhibits absorbing performance with the minimum reflection loss (RLmin) of −42.2 dB and the Effective absorption band (EAB) of 7.12 GHz. Meanwhile, the absorption peaks are mainly concentrated on X-band. Further, as the morphology changes to porous layers, the RLmin of loofah-like CCM increases to −63.8 dB, whose EAB is 7.32 GHz at 2.5 mm, and the main absorption peaks shift to Ku-band. Besides, the possible absorption mechanism of biomimetic composite membranes has been expounded. This work provides a versatile strategy for CNF/MXene composite membrane with biomimetic structures on excellent and tunable microwave absorption performance.
期刊介绍:
The Chemical Engineering Journal is an international research journal that invites contributions of original and novel fundamental research. It aims to provide an international platform for presenting original fundamental research, interpretative reviews, and discussions on new developments in chemical engineering. The journal welcomes papers that describe novel theory and its practical application, as well as those that demonstrate the transfer of techniques from other disciplines. It also welcomes reports on carefully conducted experimental work that is soundly interpreted. The main focus of the journal is on original and rigorous research results that have broad significance. The Catalysis section within the Chemical Engineering Journal focuses specifically on Experimental and Theoretical studies in the fields of heterogeneous catalysis, molecular catalysis, and biocatalysis. These studies have industrial impact on various sectors such as chemicals, energy, materials, foods, healthcare, and environmental protection.