Experimental and kinetic modeling study of α-methylnaphthalene laminar flame speeds

α-Methylnaphthalene (AMN) is the primary reference bicyclic aromatic compound of diesel, and it is commonly used as a component of diesel, kerosene and jet-fuel surrogates formulated to describe real fuel combustion kinetics. However, few experimental data on neat AMN combustion are available in the literature. This work provides the first measurements of laminar flame speed profiles of AMN/air mixtures at 1 bar varying the initial temperature from 425 to 484 K, and equivalence ratio (φ) between 0.8 and 1.35 paving the way for the kinetic study of AMN combustion chemistry at high temperatures (>1800 K). The experimental data obtained in a spherical reactor are compared with kinetic model simulations. Specifically, the AMN kinetics is implemented from its analogous monocyclic aromatic compound, i.e., toluene, through the analogy and rate rule approach. This method allows to develop kinetic mechanisms of large species from the kinetics of smaller ones characterized by analogous chemical features, namely the aromaticity and the methyl functionality in the case of toluene and AMN. In doing so, it is possible to overcome the need of high-level electronic structure calculations for the evaluation of rate constants, as their computational cost increases exponentially with the number of heavy atoms of the selected species. To assess the validity of this approach, ab initio calculations are performed to derive the rate constants of the H-atom abstraction reactions by H, OH and CH₃ radicals from both toluene and AMN. The kinetic model obtained satisfactorily agrees with the measured laminar flame speed profiles. Sensitivity and flux analyses are performed to investigate similarities and differences between the main reaction channels of toluene and AMN combustion, with the former leading to ∼6 cm/s faster flame speed at almost identical conditions (P=1 bar, T∼425 K), as evidenced by both kinetic model simulations and experimental findings.