Shailesh Dangwal , Anil Ronte , Han Lin , Ruochen Liu , Jiahua Zhu , Jong Suk Lee , Heather Gappa-Fahlenkamp , Seok-Jhin Kim
{"title":"ZIF-8膜支持硅石种子底物丙烯/丙烷分离","authors":"Shailesh Dangwal , Anil Ronte , Han Lin , Ruochen Liu , Jiahua Zhu , Jong Suk Lee , Heather Gappa-Fahlenkamp , Seok-Jhin Kim","doi":"10.1016/j.memsci.2021.119165","DOIUrl":null,"url":null,"abstract":"<div><p><span><span>Zeolitic Imidazolate Framework-8 (ZIF-8) membranes have shown great potential for effective separation of industrially important propylene/propane gas mixtures. In this work, we coated the silicalite seed nanoparticles<span> on the anodic alumina oxide (AAO) substrate in order to increase membrane-substrate bonding. ZIF-8 membrane was synthesized on a silicalite-seeded AAO substrate by secondary growth method. It was found that high quality ZIF-8 membrane was fabricated due to strong attachment of silicalite seed crystals to AAO substrates through </span></span>hydrogen bonding. Moreover, when ZnCl</span><sub>2</sub> was used as the Zn source, the ZIF-8 layer was formed with larger ZIF-8 crystal size and a more intergrown surface than the layer in which ZnNO<sub>3</sub> was used. An excellent propylene/propane separation factor of 170 was obtained in a silicalite-seeded ZIF-8 membrane with ZnCl<sub>2</sub>, which is twice that of a ZIF-8 membrane synthesized without the seeding process, and which is 3.6 times higher than a silicalite-seeded ZIF-8 membrane with ZnNO<sub>3</sub>.</p></div>","PeriodicalId":368,"journal":{"name":"Journal of Membrane Science","volume":"626 ","pages":"Article 119165"},"PeriodicalIF":8.4000,"publicationDate":"2021-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.memsci.2021.119165","citationCount":"22","resultStr":"{\"title\":\"ZIF-8 membranes supported on silicalite-seeded substrates for propylene/propane separation\",\"authors\":\"Shailesh Dangwal , Anil Ronte , Han Lin , Ruochen Liu , Jiahua Zhu , Jong Suk Lee , Heather Gappa-Fahlenkamp , Seok-Jhin Kim\",\"doi\":\"10.1016/j.memsci.2021.119165\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p><span><span>Zeolitic Imidazolate Framework-8 (ZIF-8) membranes have shown great potential for effective separation of industrially important propylene/propane gas mixtures. In this work, we coated the silicalite seed nanoparticles<span> on the anodic alumina oxide (AAO) substrate in order to increase membrane-substrate bonding. ZIF-8 membrane was synthesized on a silicalite-seeded AAO substrate by secondary growth method. It was found that high quality ZIF-8 membrane was fabricated due to strong attachment of silicalite seed crystals to AAO substrates through </span></span>hydrogen bonding. Moreover, when ZnCl</span><sub>2</sub> was used as the Zn source, the ZIF-8 layer was formed with larger ZIF-8 crystal size and a more intergrown surface than the layer in which ZnNO<sub>3</sub> was used. An excellent propylene/propane separation factor of 170 was obtained in a silicalite-seeded ZIF-8 membrane with ZnCl<sub>2</sub>, which is twice that of a ZIF-8 membrane synthesized without the seeding process, and which is 3.6 times higher than a silicalite-seeded ZIF-8 membrane with ZnNO<sub>3</sub>.</p></div>\",\"PeriodicalId\":368,\"journal\":{\"name\":\"Journal of Membrane Science\",\"volume\":\"626 \",\"pages\":\"Article 119165\"},\"PeriodicalIF\":8.4000,\"publicationDate\":\"2021-05-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/j.memsci.2021.119165\",\"citationCount\":\"22\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Membrane Science\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0376738821001174\",\"RegionNum\":1,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"ENGINEERING, CHEMICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Membrane Science","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0376738821001174","RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
ZIF-8 membranes supported on silicalite-seeded substrates for propylene/propane separation
Zeolitic Imidazolate Framework-8 (ZIF-8) membranes have shown great potential for effective separation of industrially important propylene/propane gas mixtures. In this work, we coated the silicalite seed nanoparticles on the anodic alumina oxide (AAO) substrate in order to increase membrane-substrate bonding. ZIF-8 membrane was synthesized on a silicalite-seeded AAO substrate by secondary growth method. It was found that high quality ZIF-8 membrane was fabricated due to strong attachment of silicalite seed crystals to AAO substrates through hydrogen bonding. Moreover, when ZnCl2 was used as the Zn source, the ZIF-8 layer was formed with larger ZIF-8 crystal size and a more intergrown surface than the layer in which ZnNO3 was used. An excellent propylene/propane separation factor of 170 was obtained in a silicalite-seeded ZIF-8 membrane with ZnCl2, which is twice that of a ZIF-8 membrane synthesized without the seeding process, and which is 3.6 times higher than a silicalite-seeded ZIF-8 membrane with ZnNO3.
期刊介绍：
The Journal of Membrane Science is a publication that focuses on membrane systems and is aimed at academic and industrial chemists, chemical engineers, materials scientists, and membranologists. It publishes original research and reviews on various aspects of membrane transport, membrane formation/structure, fouling, module/process design, and processes/applications. The journal primarily focuses on the structure, function, and performance of non-biological membranes but also includes papers that relate to biological membranes. The Journal of Membrane Science publishes Full Text Papers, State-of-the-Art Reviews, Letters to the Editor, and Perspectives.
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