有机催化的新概念。

S C Pan, B List
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引用次数: 0

摘要

有机催化是指使用低分子量催化剂的催化,其中金属不是催化原理或反应底物的一部分,它可以像金属催化或生物催化一样高效和选择性。该领域的重要发现包括新型Lewis碱催化的对映选择性过程,以及最近的简单Brønsted酸有机催化剂,其效率可与传统的金属基不对称Lewis酸催化剂相媲美。我们的实验室对有机催化的贡献包括一些新的和广泛有用的概念,如烯胺催化和不对称反阴离子定向催化。本实验室发现了脯氨酸催化的直接不对称分子间醛醇反应,并介绍了其他几种有机催化反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
New concepts for organocatalysis.

Organocatalysis, catalysis with low-molecular weight catalysts in which a metal is not part of the catalytic principle or the reaction substrate, can be as efficient and selective as metal- or biocatalysis. Important discoveries in this area include novel Lewis base-catalyzed enantioselective processes and, more recently, simple Brønsted acid organocatalysts that rival the efficiency of traditional metal-based asymmetric Lewis acid-catalysts. Contributions to organocatalysis from our laboratories include several new and broadly useful concepts such as enamine catalysis and asymmetric counteranion-directed catalysis. Our laboratory has discovered the proline-catalyzed direct asymmetric intermolecular aldol reaction and introduced several other organocatalytic reactions.

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