有机光伏材料中π共轭聚合物的研究进展:太阳能电池和光电探测器

IF 26 1区 化学 Q1 POLYMER SCIENCE
Chunchen Liu, Lin Shao, Shihao Chen, Zhengwei Hu, Houji Cai, Fei Huang
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引用次数: 6

摘要

π共轭聚合物具有重量轻、柔韧性好、颜色易调、可大规模溶液加工等优点,在有机光伏电池(OSCs)和有机光电探测器(OPDs)等领域具有广阔的应用前景。近三十年来,经过研究人员的不断努力,各种π共轭聚合物被开发出来,极大地将opv技术推向了一个前所未有的阶段。为了揭示聚合物结构与光学和电子性能、链间聚集和形态以及器件性能之间的关系,回顾π共轭聚合物用于opv的研究进展,特别是近年来在全聚合物太阳能电池(all-PSCs)、室内有机光伏电池(IOPVs)、厚膜OSCs、单组分有机太阳能电池(SCOSCs)和短波红外(SWIR) opd方面取得的突出成就,具有重要意义。本文综述了用于高性能opv的π共轭聚合物的一般设计策略,包括共轭主链工程、侧链工程、区域规则工程、卤素取代和分子量控制。然后,对全pscs、iopv、厚膜OSCs、SCOSCs和opd的共轭聚合物的发展进行了综述。最后,总结了opv用π共轭聚合物研究面临的挑战和未来的发展方向。因此,深入理解π共轭聚合物的设计可以促进当前OPV材料的发展,从而加速OPV技术的最终产业化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Recent Progress in π-Conjugated Polymers for Organic Photovoltaics: Solar Cells and Photodetectors

Recent Progress in π-Conjugated Polymers for Organic Photovoltaics: Solar Cells and Photodetectors

π-Conjugated polymers show promising potential in the application of organic photovoltaics, including organic solar cells (OSCs) and organic photodetectors (OPDs) because of merits of light-weight, flexibility, facilely tuned color, large-scaled solution-processability, etc. Over the past three decades, various π-conjugated polymers have been developed owing to the continuous efforts of researchers, which significantly promote the OPVs technology to an unprecedented stage. In order to reveal the relationship among polymer structures to the optical and electronic properties and interchain aggregation and morphology and finally to device performance, it is of great significance to review the progress of π-conjugated polymers for OPVs, particularly for outstanding achievements in recent all-polymer solar cells (all-PSCs), indoor organic photovoltaics (IOPVs), thick-film OSCs, single-component organic solar cells (SCOSCs) and short-wave infrared (SWIR) OPDs. This review highlights general design strategies of π-conjugated polymers for high-performance OPVs, including conjugated backbone engineering, side-chains engineering, regioregularity engineering, halogen substitution and molecular weight control. Then, the development of conjugated polymers for all-PSCs, IOPVs, thick-film OSCs, SCOSCs and OPDs has been summarized. At the end, we summarize the challenges and future directions for studying π-conjugated polymers for OPVs. Therefore, an in-depth understanding of designing π-conjugated polymers is speculated to advance the development of current OPV materials and thus accelerate the ultimate industrialization of the OPV technology.

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来源期刊
Progress in Polymer Science
Progress in Polymer Science 化学-高分子科学
CiteScore
48.70
自引率
1.10%
发文量
54
审稿时长
38 days
期刊介绍: Progress in Polymer Science is a journal that publishes state-of-the-art overview articles in the field of polymer science and engineering. These articles are written by internationally recognized authorities in the discipline, making it a valuable resource for staying up-to-date with the latest developments in this rapidly growing field. The journal serves as a link between original articles, innovations published in patents, and the most current knowledge of technology. It covers a wide range of topics within the traditional fields of polymer science, including chemistry, physics, and engineering involving polymers. Additionally, it explores interdisciplinary developing fields such as functional and specialty polymers, biomaterials, polymers in drug delivery, polymers in electronic applications, composites, conducting polymers, liquid crystalline materials, and the interphases between polymers and ceramics. The journal also highlights new fabrication techniques that are making significant contributions to the field. The subject areas covered by Progress in Polymer Science include biomaterials, materials chemistry, organic chemistry, polymers and plastics, surfaces, coatings and films, and nanotechnology. The journal is indexed and abstracted in various databases, including Materials Science Citation Index, Chemical Abstracts, Engineering Index, Current Contents, FIZ Karlsruhe, Scopus, and INSPEC.
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