高疏水性聚二甲基硅氧烷包覆膨胀蛭石吸附剂的选择性除油。

IF 4.3 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Nanomaterials Pub Date : 2021-02-02 DOI:10.3390/nano11020367
Duc Cuong Nguyen, Trung Tuyen Bui, Yeong Beom Cho, Yong Shin Kim
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引用次数: 12

摘要

利用H2O2水溶液对天然丰富的蛭石粘土进行膨胀,并用超薄聚二甲基硅氧烷(PDMS)对其表面进行易热气相沉积改性,制备了一种生态友好、低成本的吸油剂,在溢油修复中发挥了重要作用。得到的pdms包覆的膨胀蛭石(eVMT@PDMS)颗粒具有良好的疏水性和亲油性,可用于油水分离,具有大量的锥形缝孔(尺寸为0.1-100 μm),提供了巨大的吸附能力和有效的毛细驱动的集油通道。只需使用物理包装的eVMT@PDMS管(或袋),就可以在水面上下演示选择性除油。此外,这些吸附剂已成功集成并应用于桶形撇油器和自吸油泵等先进的集油装置中。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Highly Hydrophobic Polydimethylsiloxane-Coated Expanded Vermiculite Sorbents for Selective Oil Removal from Water.

Highly Hydrophobic Polydimethylsiloxane-Coated Expanded Vermiculite Sorbents for Selective Oil Removal from Water.

Highly Hydrophobic Polydimethylsiloxane-Coated Expanded Vermiculite Sorbents for Selective Oil Removal from Water.

Highly Hydrophobic Polydimethylsiloxane-Coated Expanded Vermiculite Sorbents for Selective Oil Removal from Water.

Naturally abundant vermiculite clay was expanded by using an aqueous solution of H2O2 and its surface was modified with ultra-thin polydimethylsiloxane (PDMS) using facile thermal vapor deposition to prepare an ecologically friendly, low-cost oil sorbent that plays an important role in oil spillage remediation. The resulting PDMS-coated expanded vermiculite (eVMT@PDMS) particles exhibited adequate hydrophobicity and oleophilicity for oil/water separation, with numerous conical slit pores (a size of 0.1-100 μm) providing a great sorption capacity and an efficient capillarity-driven flow pathway for oil collection. Simply with using a physically-packed eVMT@PDMS tube (or pouch), selective oil removals were demonstrated above and beneath the surface of the water. Furthermore, these sorbents were successfully integrated and then applied to the advanced oil-collecting devices such as a barrel-shaped oil skimmer and a self-primed oil pump.

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来源期刊
Nanomaterials
Nanomaterials NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
8.50
自引率
9.40%
发文量
3841
审稿时长
14.22 days
期刊介绍: Nanomaterials (ISSN 2076-4991) is an international and interdisciplinary scholarly open access journal. It publishes reviews, regular research papers, communications, and short notes that are relevant to any field of study that involves nanomaterials, with respect to their science and application. Thus, theoretical and experimental articles will be accepted, along with articles that deal with the synthesis and use of nanomaterials. Articles that synthesize information from multiple fields, and which place discoveries within a broader context, will be preferred. There is no restriction on the length of the papers. Our aim is to encourage scientists to publish their experimental and theoretical research in as much detail as possible. Full experimental or methodical details, or both, must be provided for research articles. Computed data or files regarding the full details of the experimental procedure, if unable to be published in a normal way, can be deposited as supplementary material. Nanomaterials is dedicated to a high scientific standard. All manuscripts undergo a rigorous reviewing process and decisions are based on the recommendations of independent reviewers.
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