{"title":"聚合物/无机杂化电解质的简单可扩展加工方法","authors":"Shintaro Kitajima, Wonsung Choi, Dongmin Im","doi":"10.1016/j.compscitech.2020.108249","DOIUrl":null,"url":null,"abstract":"<div><p><span>The development of polymer/inorganic composite membrane<span> hybrid electrolytes for use in lithium-ion batteries has significantly advanced the innovation of energy storage devices. These membranes consist of monolayered Li-ion-conducting particles that are firmly embedded in an insulating polymer matrix<span> and can improve conductivity and </span></span></span>mechanical characteristics<span>. However, the scalability of producing one-particle-thick membranes remains a challenge. Here, we evaluate three different simple processes that may be used to produce composite membranes by examining scanning electron microscope<span> images and measuring conductivity. The conductivity of the membrane produced by the optimal method was 0.49 mS/cm at 20 °C, which is approximately 5.5 times higher than that of a commercially produced LATP-sintered disk. The optimal process described here could be used in industrial applications of both all-solid batteries in electric vehicles and flexible all-solid-state batteries in wearable devices.</span></span></p></div>","PeriodicalId":283,"journal":{"name":"Composites Science and Technology","volume":null,"pages":null},"PeriodicalIF":8.3000,"publicationDate":"2020-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.compscitech.2020.108249","citationCount":"1","resultStr":"{\"title\":\"Simple scalable processing method for a polymer/inorganic hybridized electrolyte\",\"authors\":\"Shintaro Kitajima, Wonsung Choi, Dongmin Im\",\"doi\":\"10.1016/j.compscitech.2020.108249\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p><span>The development of polymer/inorganic composite membrane<span> hybrid electrolytes for use in lithium-ion batteries has significantly advanced the innovation of energy storage devices. These membranes consist of monolayered Li-ion-conducting particles that are firmly embedded in an insulating polymer matrix<span> and can improve conductivity and </span></span></span>mechanical characteristics<span>. However, the scalability of producing one-particle-thick membranes remains a challenge. Here, we evaluate three different simple processes that may be used to produce composite membranes by examining scanning electron microscope<span> images and measuring conductivity. The conductivity of the membrane produced by the optimal method was 0.49 mS/cm at 20 °C, which is approximately 5.5 times higher than that of a commercially produced LATP-sintered disk. The optimal process described here could be used in industrial applications of both all-solid batteries in electric vehicles and flexible all-solid-state batteries in wearable devices.</span></span></p></div>\",\"PeriodicalId\":283,\"journal\":{\"name\":\"Composites Science and Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":8.3000,\"publicationDate\":\"2020-09-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/j.compscitech.2020.108249\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Composites Science and Technology\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0266353820306217\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, COMPOSITES\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Composites Science and Technology","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0266353820306217","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, COMPOSITES","Score":null,"Total":0}
Simple scalable processing method for a polymer/inorganic hybridized electrolyte
The development of polymer/inorganic composite membrane hybrid electrolytes for use in lithium-ion batteries has significantly advanced the innovation of energy storage devices. These membranes consist of monolayered Li-ion-conducting particles that are firmly embedded in an insulating polymer matrix and can improve conductivity and mechanical characteristics. However, the scalability of producing one-particle-thick membranes remains a challenge. Here, we evaluate three different simple processes that may be used to produce composite membranes by examining scanning electron microscope images and measuring conductivity. The conductivity of the membrane produced by the optimal method was 0.49 mS/cm at 20 °C, which is approximately 5.5 times higher than that of a commercially produced LATP-sintered disk. The optimal process described here could be used in industrial applications of both all-solid batteries in electric vehicles and flexible all-solid-state batteries in wearable devices.
期刊介绍:
Composites Science and Technology publishes refereed original articles on the fundamental and applied science of engineering composites. The focus of this journal is on polymeric matrix composites with reinforcements/fillers ranging from nano- to macro-scale. CSTE encourages manuscripts reporting unique, innovative contributions to the physics, chemistry, materials science and applied mechanics aspects of advanced composites.
Besides traditional fiber reinforced composites, novel composites with significant potential for engineering applications are encouraged.