Y. Naciri , A. Hsini , Z. Ajmal , J.A. Navío , B. Bakiz , A. Albourine , M. Ezahri , A. Benlhachemi
{"title":"π共轭材料增强BiPO4光催化性能的研究进展","authors":"Y. Naciri , A. Hsini , Z. Ajmal , J.A. Navío , B. Bakiz , A. Albourine , M. Ezahri , A. Benlhachemi","doi":"10.1016/j.cis.2020.102160","DOIUrl":null,"url":null,"abstract":"<div><p><span>Semiconductor photocatalysis<span> is regarded as most privileged solution for energy conversion and environmental application. Recently, photocatalysis methods using bismuth-based photocatalysts, such as BiPO</span></span><sub>4</sub><span>, have been extensively investigated owing to their superior efficacy regarding organic pollutant degradation and their further mineralization into CO</span><sub>2</sub> and H<sub>2</sub>O. It is well known that BiPO<sub>4</sub> monoclinic phase exhibited better photocatalytic performance compared to Degussa (Evonik) P25 TiO<sub>2</sub> in term of ultraviolet light driven organic pollutants degradation. However, its wide band gap, poor adsorptive performance and large size make BiPO<sub>4</sub><span> less active under visible light irradiation. However, extensive research works have been conducted in the past with the aim of improving visible light driven BiPO</span><sub>4</sub><span> activity by constructing a series of heterostructures, mainly coupled with π-conjugated architecture (e.g., conductive polymer, dye sensitization and carbonaceous materials). However, a critical review of modified BiPO</span><sub>4</sub> systems using π-conjugated materials has not been published to date. Therefore, this current review article was designed with the aim of presenting a brief current state-of-the-art towards synthesis methods of BiPO<sub>4</sub><span> in the first section, with an especial focuses onto its crystal-microstructure, optical and photocatalytic properties. Moreover, the most relevant strategies that have been employed to improve its photocatalytic activities are then addressed as the main part of this review. Finally, the last section presents ongoing challenges and perspectives for modified BiPO</span><sub>4</sub> systems using π–conjugated materials.</p></div>","PeriodicalId":239,"journal":{"name":"Advances in Colloid and Interface Science","volume":"280 ","pages":"Article 102160"},"PeriodicalIF":15.9000,"publicationDate":"2020-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.cis.2020.102160","citationCount":"77","resultStr":"{\"title\":\"Recent progress on the enhancement of photocatalytic properties of BiPO4 using π–conjugated materials\",\"authors\":\"Y. Naciri , A. Hsini , Z. Ajmal , J.A. Navío , B. Bakiz , A. Albourine , M. Ezahri , A. Benlhachemi\",\"doi\":\"10.1016/j.cis.2020.102160\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p><span>Semiconductor photocatalysis<span> is regarded as most privileged solution for energy conversion and environmental application. Recently, photocatalysis methods using bismuth-based photocatalysts, such as BiPO</span></span><sub>4</sub><span>, have been extensively investigated owing to their superior efficacy regarding organic pollutant degradation and their further mineralization into CO</span><sub>2</sub> and H<sub>2</sub>O. It is well known that BiPO<sub>4</sub> monoclinic phase exhibited better photocatalytic performance compared to Degussa (Evonik) P25 TiO<sub>2</sub> in term of ultraviolet light driven organic pollutants degradation. However, its wide band gap, poor adsorptive performance and large size make BiPO<sub>4</sub><span> less active under visible light irradiation. However, extensive research works have been conducted in the past with the aim of improving visible light driven BiPO</span><sub>4</sub><span> activity by constructing a series of heterostructures, mainly coupled with π-conjugated architecture (e.g., conductive polymer, dye sensitization and carbonaceous materials). However, a critical review of modified BiPO</span><sub>4</sub> systems using π-conjugated materials has not been published to date. Therefore, this current review article was designed with the aim of presenting a brief current state-of-the-art towards synthesis methods of BiPO<sub>4</sub><span> in the first section, with an especial focuses onto its crystal-microstructure, optical and photocatalytic properties. Moreover, the most relevant strategies that have been employed to improve its photocatalytic activities are then addressed as the main part of this review. Finally, the last section presents ongoing challenges and perspectives for modified BiPO</span><sub>4</sub> systems using π–conjugated materials.</p></div>\",\"PeriodicalId\":239,\"journal\":{\"name\":\"Advances in Colloid and Interface Science\",\"volume\":\"280 \",\"pages\":\"Article 102160\"},\"PeriodicalIF\":15.9000,\"publicationDate\":\"2020-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/j.cis.2020.102160\",\"citationCount\":\"77\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advances in Colloid and Interface Science\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S000186862030035X\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advances in Colloid and Interface Science","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S000186862030035X","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Recent progress on the enhancement of photocatalytic properties of BiPO4 using π–conjugated materials
Semiconductor photocatalysis is regarded as most privileged solution for energy conversion and environmental application. Recently, photocatalysis methods using bismuth-based photocatalysts, such as BiPO4, have been extensively investigated owing to their superior efficacy regarding organic pollutant degradation and their further mineralization into CO2 and H2O. It is well known that BiPO4 monoclinic phase exhibited better photocatalytic performance compared to Degussa (Evonik) P25 TiO2 in term of ultraviolet light driven organic pollutants degradation. However, its wide band gap, poor adsorptive performance and large size make BiPO4 less active under visible light irradiation. However, extensive research works have been conducted in the past with the aim of improving visible light driven BiPO4 activity by constructing a series of heterostructures, mainly coupled with π-conjugated architecture (e.g., conductive polymer, dye sensitization and carbonaceous materials). However, a critical review of modified BiPO4 systems using π-conjugated materials has not been published to date. Therefore, this current review article was designed with the aim of presenting a brief current state-of-the-art towards synthesis methods of BiPO4 in the first section, with an especial focuses onto its crystal-microstructure, optical and photocatalytic properties. Moreover, the most relevant strategies that have been employed to improve its photocatalytic activities are then addressed as the main part of this review. Finally, the last section presents ongoing challenges and perspectives for modified BiPO4 systems using π–conjugated materials.
期刊介绍:
"Advances in Colloid and Interface Science" is an international journal that focuses on experimental and theoretical developments in interfacial and colloidal phenomena. The journal covers a wide range of disciplines including biology, chemistry, physics, and technology.
The journal accepts review articles on any topic within the scope of colloid and interface science. These articles should provide an in-depth analysis of the subject matter, offering a critical review of the current state of the field. The author's informed opinion on the topic should also be included. The manuscript should compare and contrast ideas found in the reviewed literature and address the limitations of these ideas.
Typically, the articles published in this journal are written by recognized experts in the field.