Multifunctional and thermoresponsive methylcellulose composite hydrogels with photothermal effect

Multifunctional and thermoresponsive hydrogels can be used as soft materials in various medical applications, such as beauty devices, drug delivery, and near-infrared (NIR) lasers. In this study, methylcellulose (MC) composite hydrogels containing tannic acid (TA) and Fe³⁺ were prepared via a simple, fast process. The MC composite hydrogel contains hydrogen bonds between the MC polymer and TA and coordination bonds between TA and Fe³⁺, without losing the reversible thermogelation properties of the MC polymer. The gelation rates and mechanical properties of the MC composite hydrogel were controlled by varying its TA and Fe³⁺ contents. In particular, the hydrogel with a TA–Fe chelating complex showed an excellent photothermal effect, indicating its potential application in cosmetic beauty devices. It also exhibited UV-blocking, antioxidant, and antibacterial properties owing to the multifunctional TA. The facile processing of these MC/TA/Fe hydrogels provides new opportunities for biomedical applications and beauty devices employing NIR laser therapy.