NMC电池的回收和材料再利用评估

IF 7.4 2区 工程技术 Q1 ENERGY & FUELS
Aleksandra Skalba, Angad Panesar
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引用次数: 0

摘要

镍锰钴(NMC)电池的可持续回收取决于阴极化学、回收途径和材料特异性回收之间的相互作用。本研究将环境足迹(EF 3.0)/产品环境足迹(PEF)框架跨16个影响类别应用于NMC 532、622和811,使用固定的40千瓦时参考配置、化学特定材料库存、具有代表性的Ecoinvent v3.8湿法冶金(HMP)和火法冶金(PMP)处理数据集,以及文献衍生的高回收率和低回收率情景。在1:1闭环替代假设下,回收后的负担将直接处理影响与不完全回收后所需的原始材料充值相结合。从NMC 532过渡到811可使原始材料单次得分降低约18%,而相应的直接回收变化为约10%。在治疗阶段,HMP的单分PEF比PMP低19%,并且在16个类别中的12个类别中较低。在高回收率条件下,HMP的回收后负担最低,比相应的原始材料基线低96-97%,而PMP的PEF降低92-93%。恢复损失可以逆转路由排序;对于HMP,石墨不完全回收是残余原始材料负荷的主要驱动因素。因此,可转移的发现是一个依赖于阶段的决策层次:化学主要控制初级材料负担,路线选择控制处理阶段的权衡,特定材料的回收可以主导闭环结果。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Assessment of recycling and material reuse in NMC batteries
Sustainable recycling of nickel–manganese–cobalt (NMC) batteries depends on the interaction between cathode chemistry, recycling pathway and material-specific recovery. This study applies the Environmental Footprint (EF 3.0)/Product Environmental Footprint (PEF) framework across 16 impact categories to NMC 532, 622 and 811 using a fixed 40 kWh reference configuration, chemistry-specific material inventories, representative Ecoinvent v3.8 hydrometallurgical (HMP) and pyrometallurgical (PMP) treatment datasets, and literature-derived high- and low-recovery scenarios. Post-recycling burdens combine direct treatment impacts with the virgin-material top-up required after incomplete recovery under a 1:1 closed-loop substitution assumption. Moving from NMC 532 to 811 reduces the virgin-material single score by ∼ 18%, whereas the corresponding direct recycling change is ∼ 10%. At the treatment stage, HMP gives a 19% lower single-score PEF than PMP and is lower in 12 of 16 categories. Under high-recovery conditions, HMP gives the lowest post-recycling burden, ∼96–97% below the corresponding virgin-material baseline, while PMP gives 92–93% lower PEF. Recovery losses can reverse the route ranking; for HMP, incomplete graphite recovery is a dominant driver of residual virgin-material burden. The transferable finding is therefore a stage-dependent decision hierarchy: chemistry primarily governs primary-material burden, route selection governs treatment-stage trade-offs, and material-specific recovery can dominate the closed-loop outcome.
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来源期刊
Sustainable Energy Technologies and Assessments
Sustainable Energy Technologies and Assessments Energy-Renewable Energy, Sustainability and the Environment
CiteScore
12.70
自引率
12.50%
发文量
1091
期刊介绍: Encouraging a transition to a sustainable energy future is imperative for our world. Technologies that enable this shift in various sectors like transportation, heating, and power systems are of utmost importance. Sustainable Energy Technologies and Assessments welcomes papers focusing on a range of aspects and levels of technological advancements in energy generation and utilization. The aim is to reduce the negative environmental impact associated with energy production and consumption, spanning from laboratory experiments to real-world applications in the commercial sector.
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