Na（CHSO）·B(OH)：具有大双折射的硼酸-苯磺酸盐晶体

IF 3.3 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2026-10-15 DOI:10.1039/d6dt02161a

Lei Wu,Enshen Wang,Qun Jing,Xue Yu,Xiaoyu Dong,Zhaohui Chen

引用次数: 0

摘要

Na（C6H5SO3）·B(OH)3是第一个硼酸-苯磺酸盐化合物，在单斜晶系中结晶，具有独特的2[Na(SO3)B(OH)3]∞双层结构。这种有序结构产生了显著的0.150@546 nm双折射。本工作为紫外双折射晶体的发展建立了一种新的混合阴离子体系。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Na(CHSO)·B(OH): a borate–benzenesulfonate crystal with large birefringence

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Na(CHSO)·B(OH): a borate–benzenesulfonate crystal with large birefringence

Na(C6H5SO3)·B(OH)3, the first borate–benzenesulfonate compound, crystallizes in a monoclinic system featuring unique 2[Na(SO3)B(OH)3]∞ double layers. This ordered structure yields a significant birefringence of 0.150@546 nm. This work establishes a new mixed-anion system for the development of UV birefringent crystals.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.