氧化亚硝基dielo - alder反应及杂络合重排法合成恶二氮[2.2.2]辛烯

IF 2.3 4区化学 Q1 CHEMISTRY, ORGANIC

Asian Journal of Organic Chemistry Pub Date : 2026-09-30 DOI:10.1002/ajoc.70557

Caterina Campinoti, Lukas Andru, Simona Marchetti, Mauro Pineschi, Fabio Bellina, Antonio Del Vecchio, Marco Lessi

{"title":"氧化亚硝基dielo - alder反应及杂络合重排法合成恶二氮[2.2.2]辛烯","authors":"Caterina Campinoti, Lukas Andru, Simona Marchetti, Mauro Pineschi, Fabio Bellina, Antonio Del Vecchio, Marco Lessi","doi":"10.1002/ajoc.70557","DOIUrl":null,"url":null,"abstract":"<div>\n \n <p>The present work reports a straightforward approach for the mechanochemical oxidative nitroso Diels–Alder (DA) reaction for the rapid synthesis of oxadiazo[2.2.2]octenes and a mechanochemical [3+3] hetero-Cope rearrangement to access the corresponding dioxazines within reduced reaction time (up to 1.5 min and 1.5 h, respectively), high yields and reproducibility toward different functional groups.</p>\n </div>","PeriodicalId":130,"journal":{"name":"Asian Journal of Organic Chemistry","volume":"15 10","pages":""},"PeriodicalIF":2.3000,"publicationDate":"2026-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Mechanochemical Synthesis and Functionalization of Oxadiazo[2.2.2]octenes Through Oxidative Nitroso Diels–Alder Reaction and Hetero-Cope Rearrangement\",\"authors\":\"Caterina Campinoti, Lukas Andru, Simona Marchetti, Mauro Pineschi, Fabio Bellina, Antonio Del Vecchio, Marco Lessi\",\"doi\":\"10.1002/ajoc.70557\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div>\\n \\n <p>The present work reports a straightforward approach for the mechanochemical oxidative nitroso Diels–Alder (DA) reaction for the rapid synthesis of oxadiazo[2.2.2]octenes and a mechanochemical [3+3] hetero-Cope rearrangement to access the corresponding dioxazines within reduced reaction time (up to 1.5 min and 1.5 h, respectively), high yields and reproducibility toward different functional groups.</p>\\n </div>\",\"PeriodicalId\":130,\"journal\":{\"name\":\"Asian Journal of Organic Chemistry\",\"volume\":\"15 10\",\"pages\":\"\"},\"PeriodicalIF\":2.3000,\"publicationDate\":\"2026-09-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Asian Journal of Organic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ajoc.70557\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, ORGANIC\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Asian Journal of Organic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ajoc.70557","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}

引用次数: 0

摘要

本研究报道了一种直接的机械化学氧化亚硝基Diels-Alder （DA）反应快速合成恶二氮[2.2.2]辛烯和机械化学[3+3]杂络合重排获得相应的二恶嗪的方法，反应时间缩短（分别为1.5 min和1.5 h），产率高，对不同官能团的重现性好。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Mechanochemical Synthesis and Functionalization of Oxadiazo[2.2.2]octenes Through Oxidative Nitroso Diels–Alder Reaction and Hetero-Cope Rearrangement

The present work reports a straightforward approach for the mechanochemical oxidative nitroso Diels–Alder (DA) reaction for the rapid synthesis of oxadiazo[2.2.2]octenes and a mechanochemical [3+3] hetero-Cope rearrangement to access the corresponding dioxazines within reduced reaction time (up to 1.5 min and 1.5 h, respectively), high yields and reproducibility toward different functional groups.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Asian Journal of Organic Chemistry CHEMISTRY, ORGANIC-

CiteScore

4.70

自引率

3.70%

发文量

372

期刊介绍： Organic chemistry is the fundamental science that stands at the heart of chemistry, biology, and materials science. Research in these areas is vigorous and truly international, with three major regions making almost equal contributions: America, Europe and Asia. Asia now has its own top international organic chemistry journal—the Asian Journal of Organic Chemistry (AsianJOC) The AsianJOC is designed to be a top-ranked international research journal and publishes primary research as well as critical secondary information from authors across the world. The journal covers organic chemistry in its entirety. Authors and readers come from academia, the chemical industry, and government laboratories.