关于“在T = (293.15-313.15) K时乙酸苄酯与芳香异构体（异丁基苯、对丁基苯、叔丁基苯）二元液体混合物的热力学性质”的评论

IF 1.3 4区化学 Q4 CHEMISTRY, PHYSICAL

Journal of Solution Chemistry Pub Date : 2026-05-24 DOI:10.1007/s10953-026-01601-4

Yuuki Uemura, Anika Varadharajan, William E. Acree Jr.

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引用次数: 0

摘要

对Panem和同事在他们发表的论文中报告的体积特性进行了争论。对于所研究的三个双星系统中的两个，作者计算的过量摩尔体积的数值\(V_{m}^\text{E}\)被发现与论文中报告的测量密度数据不一致。评注中提供的意见引起了人们对已发表的密度数据质量的关注。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Comments on “Thermodynamic Properties of Binary Liquid Mixtures of Benzyl Acetate and Aromatic Isomers (iso-Butylbenzene, sec‑Butylbenzene, tert‑Butylbenzene) at T = (293.15—313.15) K”

A polemic is given regarding the volumetric properties that Panem and coworkers reported in their published paper. For two of the three binary systems studied, the authors’ calculated numerical values of the excess molar volumes, \(V_{m}^\text{E}\) , were found to be inconsistent with the measured density data reported in the paper. The observations provided in the commentary raise concerns regarding the quality of the published density data.

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来源期刊

Journal of Solution Chemistry 化学-物理化学

CiteScore

2.30

自引率

0.00%

发文量

审稿时长

3-8 weeks

期刊介绍： Journal of Solution Chemistry offers a forum for research on the physical chemistry of liquid solutions in such fields as physical chemistry, chemical physics, molecular biology, statistical mechanics, biochemistry, and biophysics. The emphasis is on papers in which the solvent plays a dominant rather than incidental role. Featured topics include experimental investigations of the dielectric, spectroscopic, thermodynamic, transport, or relaxation properties of both electrolytes and nonelectrolytes in liquid solutions.