有机叠氮化物与线性铬硅酰胺反应的跟踪

IF 1.8 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

European Journal of Inorganic Chemistry Pub Date : 2026-06-24 Epub Date: 2026-05-15 DOI:10.1002/ejic.70226

Andres Gonzalez, Sophie Schäfer, Ting-Yi Chen, Serhiy Demeshko, Franc Meyer, C. Gunnar Werncke

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引用次数: 0

摘要

有机叠氮化物与线性铬(I)硅酰胺的反应导致观察到罕见的单体和二聚亚胺铬配合物，以及不稳定的叠氮化物加合物。此外，本文还报道了第一个由线性铬（II）硅酰胺与酰基肼或Me3NO反应得到的三角氧化铬配合物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Tracking the Reaction of Organoazides with Linear Chromium Silylamides

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Tracking the Reaction of Organoazides with Linear Chromium Silylamides

The reaction of organoazides with a linear chromium(I) silylamide leads to the observation of rare monomeric and dimeric imido chromium complexes, as well as labile azide adducts. Further, the first trigonal chromium oxide complex is reported, obtained from the reaction of a linear chromium(II) silylamide with either acylazide or Me₃NO.

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来源期刊

European Journal of Inorganic Chemistry 化学-无机化学与核化学

CiteScore

4.30

自引率

4.30%

发文量

419

审稿时长

1.3 months

期刊介绍： The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.