Alessandro Petroccia, Francesco Giuntoli, Alissa Kotowski, Gianmarco Buono, Alireza Chogani, Eric Hellebrand, Lucia Pappalardo, Ivan Callegari
{"title":"用石榴石显微结构跟踪剪切带脱水反应和化石流体通量","authors":"Alessandro Petroccia, Francesco Giuntoli, Alissa Kotowski, Gianmarco Buono, Alireza Chogani, Eric Hellebrand, Lucia Pappalardo, Ivan Callegari","doi":"10.1111/jmg.70042","DOIUrl":null,"url":null,"abstract":"<p>Shear zones act as preferential fluid pathways during prograde and retrograde stages of metamorphism. Nonetheless, we still have limited knowledge of the drainage and permeability of natural settings. The preserved signature of fluid in exhumed rocks provides insights into fluid flow during burial and exhumation. This study investigates fluid flow processes recorded by garnet in quartz-schists from the As Sheik shear zone (Saih Hatat window, NE Oman). We observed garnet as equant, oblate and honeycomb (i.e., skeletal) shapes that document distinct fluid-related growth stages from peak-pressure to early exhumation, both occurring at eclogite facies conditions. Garnet nucleated at 2.0–2.2 GPa and 500°C–550°C after the chloritoid-out dehydration reaction. Subsequent decompression and heating (1.3–1.5 GPa, 600°C–650°C) promoted further fluid release and honeycomb garnet growth. We infer that dissolution, transport and precipitation rates primarily influenced whether garnets grew as oblate grains (i.e., as pseudomorphs on peak-pressure chloritoid grains) or newly nucleated equant grains. Honeycomb garnet was interpreted to show the permeability network that records migration and drainage of fluid. This internally produced fluid escaped from the shear zone using pre-existing grain boundaries and reaction-formed pathways. Assuming 1 km of shear zone thickness, we computed a time-integrated fluid flux of ~34 m<sup>3</sup> m<sup>−2</sup> for the entire duration of garnet growth. This study highlights garnet morphology as a tracer of transient fluid pathways during a burial–exhumation cycle of an eclogitic shear zone. The close connection between garnet morphology and fluids calls for a re-evaluation of similar microstructures in different tectonic settings.</p>","PeriodicalId":16472,"journal":{"name":"Journal of Metamorphic Geology","volume":"44 5","pages":"394-414"},"PeriodicalIF":3.4000,"publicationDate":"2026-06-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.70042","citationCount":"0","resultStr":"{\"title\":\"Tracking Dehydration Reactions and Fossil Fluid Flux in Shear Zones Using Garnet Microstructures\",\"authors\":\"Alessandro Petroccia, Francesco Giuntoli, Alissa Kotowski, Gianmarco Buono, Alireza Chogani, Eric Hellebrand, Lucia Pappalardo, Ivan Callegari\",\"doi\":\"10.1111/jmg.70042\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Shear zones act as preferential fluid pathways during prograde and retrograde stages of metamorphism. Nonetheless, we still have limited knowledge of the drainage and permeability of natural settings. The preserved signature of fluid in exhumed rocks provides insights into fluid flow during burial and exhumation. This study investigates fluid flow processes recorded by garnet in quartz-schists from the As Sheik shear zone (Saih Hatat window, NE Oman). We observed garnet as equant, oblate and honeycomb (i.e., skeletal) shapes that document distinct fluid-related growth stages from peak-pressure to early exhumation, both occurring at eclogite facies conditions. Garnet nucleated at 2.0–2.2 GPa and 500°C–550°C after the chloritoid-out dehydration reaction. Subsequent decompression and heating (1.3–1.5 GPa, 600°C–650°C) promoted further fluid release and honeycomb garnet growth. We infer that dissolution, transport and precipitation rates primarily influenced whether garnets grew as oblate grains (i.e., as pseudomorphs on peak-pressure chloritoid grains) or newly nucleated equant grains. Honeycomb garnet was interpreted to show the permeability network that records migration and drainage of fluid. This internally produced fluid escaped from the shear zone using pre-existing grain boundaries and reaction-formed pathways. Assuming 1 km of shear zone thickness, we computed a time-integrated fluid flux of ~34 m<sup>3</sup> m<sup>−2</sup> for the entire duration of garnet growth. This study highlights garnet morphology as a tracer of transient fluid pathways during a burial–exhumation cycle of an eclogitic shear zone. The close connection between garnet morphology and fluids calls for a re-evaluation of similar microstructures in different tectonic settings.</p>\",\"PeriodicalId\":16472,\"journal\":{\"name\":\"Journal of Metamorphic Geology\",\"volume\":\"44 5\",\"pages\":\"394-414\"},\"PeriodicalIF\":3.4000,\"publicationDate\":\"2026-06-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1111/jmg.70042\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Metamorphic Geology\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1111/jmg.70042\",\"RegionNum\":2,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2026/5/3 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"Q1\",\"JCRName\":\"GEOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Metamorphic Geology","FirstCategoryId":"89","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1111/jmg.70042","RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2026/5/3 0:00:00","PubModel":"Epub","JCR":"Q1","JCRName":"GEOLOGY","Score":null,"Total":0}
Tracking Dehydration Reactions and Fossil Fluid Flux in Shear Zones Using Garnet Microstructures
Shear zones act as preferential fluid pathways during prograde and retrograde stages of metamorphism. Nonetheless, we still have limited knowledge of the drainage and permeability of natural settings. The preserved signature of fluid in exhumed rocks provides insights into fluid flow during burial and exhumation. This study investigates fluid flow processes recorded by garnet in quartz-schists from the As Sheik shear zone (Saih Hatat window, NE Oman). We observed garnet as equant, oblate and honeycomb (i.e., skeletal) shapes that document distinct fluid-related growth stages from peak-pressure to early exhumation, both occurring at eclogite facies conditions. Garnet nucleated at 2.0–2.2 GPa and 500°C–550°C after the chloritoid-out dehydration reaction. Subsequent decompression and heating (1.3–1.5 GPa, 600°C–650°C) promoted further fluid release and honeycomb garnet growth. We infer that dissolution, transport and precipitation rates primarily influenced whether garnets grew as oblate grains (i.e., as pseudomorphs on peak-pressure chloritoid grains) or newly nucleated equant grains. Honeycomb garnet was interpreted to show the permeability network that records migration and drainage of fluid. This internally produced fluid escaped from the shear zone using pre-existing grain boundaries and reaction-formed pathways. Assuming 1 km of shear zone thickness, we computed a time-integrated fluid flux of ~34 m3 m−2 for the entire duration of garnet growth. This study highlights garnet morphology as a tracer of transient fluid pathways during a burial–exhumation cycle of an eclogitic shear zone. The close connection between garnet morphology and fluids calls for a re-evaluation of similar microstructures in different tectonic settings.
期刊介绍:
The journal, which is published nine times a year, encompasses the entire range of metamorphic studies, from the scale of the individual crystal to that of lithospheric plates, including regional studies of metamorphic terranes, modelling of metamorphic processes, microstructural and deformation studies in relation to metamorphism, geochronology and geochemistry in metamorphic systems, the experimental study of metamorphic reactions, properties of metamorphic minerals and rocks and the economic aspects of metamorphic terranes.