Yilu Du, Hui Wang, Jiangtao Ji, Xin Jin, Yang Song, Hao Zhang, Zhi Chen
{"title":"花生壳制备的氧化石墨烯改性活性炭去除水溶液中的Cd2+","authors":"Yilu Du, Hui Wang, Jiangtao Ji, Xin Jin, Yang Song, Hao Zhang, Zhi Chen","doi":"10.25165/j.ijabe.20231605.8046","DOIUrl":null,"url":null,"abstract":"Graphene oxide (GO) was prepared by a modified Hummers method using peanut shells and natural graphite, and graphene oxide modified peanut shells activated carbon composites (GO-AC) were synthesized by co-pyrolysis. The optimal preparation conditions of AC were screened by response surface methodology (RSM) to optimize the preparation process. The results showed that the surface of GO-AC had more micropores and larger specific surface area, increased the surface adsorption sites and had more oxygen-containing functional groups. The adsorption process was mainly based on chemisorption, and the adsorption capacity was 3.45 and 1.30 times higher than that of BC (45.16 mg/g) and AC (119.21 mg/g), respectively. After six adsorption-desorption cycle tests, the adsorption amount of Cd2+ by GO-AC was still as high as 89.26 mg/g, with a percentage increase of 93.5% and 365% compared to BC (19.18 mg/g) and AC (46.13 mg/g), respectively, with good reusability. The research can provide a useful reference for the high value-added conversion of waste biomass, and GO-AC loading modified with significant adsorption of Cd2+ has good potential for application as a novel and low-cost adsorbent. Keywords: graphene oxide-modified biochar, response surface optimization, adsorption, heavy metal DOI: 10.25165/j.ijabe.20231605.8046 Citation: Du Y L, Wang H, Ji J T, Jin X, Song Y, Zhang H, et al. Removal of Cd2+ from aqueous solution using graphene oxide modified activate carbon derived from peanut shell. Int J Agric & Biol Eng, 2023; 16(5): 226–235.","PeriodicalId":13895,"journal":{"name":"International Journal of Agricultural and Biological Engineering","volume":"16 5","pages":"222-235"},"PeriodicalIF":3.1000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ijabe.org/index.php/ijabe/article/download/8046/pdf","citationCount":"3","resultStr":"{\"title\":\"Removal of Cd2+ from aqueous solution using graphene oxide modified activate carbon derived from peanut shell\",\"authors\":\"Yilu Du, Hui Wang, Jiangtao Ji, Xin Jin, Yang Song, Hao Zhang, Zhi Chen\",\"doi\":\"10.25165/j.ijabe.20231605.8046\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Graphene oxide (GO) was prepared by a modified Hummers method using peanut shells and natural graphite, and graphene oxide modified peanut shells activated carbon composites (GO-AC) were synthesized by co-pyrolysis. The optimal preparation conditions of AC were screened by response surface methodology (RSM) to optimize the preparation process. The results showed that the surface of GO-AC had more micropores and larger specific surface area, increased the surface adsorption sites and had more oxygen-containing functional groups. The adsorption process was mainly based on chemisorption, and the adsorption capacity was 3.45 and 1.30 times higher than that of BC (45.16 mg/g) and AC (119.21 mg/g), respectively. After six adsorption-desorption cycle tests, the adsorption amount of Cd2+ by GO-AC was still as high as 89.26 mg/g, with a percentage increase of 93.5% and 365% compared to BC (19.18 mg/g) and AC (46.13 mg/g), respectively, with good reusability. The research can provide a useful reference for the high value-added conversion of waste biomass, and GO-AC loading modified with significant adsorption of Cd2+ has good potential for application as a novel and low-cost adsorbent. Keywords: graphene oxide-modified biochar, response surface optimization, adsorption, heavy metal DOI: 10.25165/j.ijabe.20231605.8046 Citation: Du Y L, Wang H, Ji J T, Jin X, Song Y, Zhang H, et al. Removal of Cd2+ from aqueous solution using graphene oxide modified activate carbon derived from peanut shell. 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Removal of Cd2+ from aqueous solution using graphene oxide modified activate carbon derived from peanut shell
Graphene oxide (GO) was prepared by a modified Hummers method using peanut shells and natural graphite, and graphene oxide modified peanut shells activated carbon composites (GO-AC) were synthesized by co-pyrolysis. The optimal preparation conditions of AC were screened by response surface methodology (RSM) to optimize the preparation process. The results showed that the surface of GO-AC had more micropores and larger specific surface area, increased the surface adsorption sites and had more oxygen-containing functional groups. The adsorption process was mainly based on chemisorption, and the adsorption capacity was 3.45 and 1.30 times higher than that of BC (45.16 mg/g) and AC (119.21 mg/g), respectively. After six adsorption-desorption cycle tests, the adsorption amount of Cd2+ by GO-AC was still as high as 89.26 mg/g, with a percentage increase of 93.5% and 365% compared to BC (19.18 mg/g) and AC (46.13 mg/g), respectively, with good reusability. The research can provide a useful reference for the high value-added conversion of waste biomass, and GO-AC loading modified with significant adsorption of Cd2+ has good potential for application as a novel and low-cost adsorbent. Keywords: graphene oxide-modified biochar, response surface optimization, adsorption, heavy metal DOI: 10.25165/j.ijabe.20231605.8046 Citation: Du Y L, Wang H, Ji J T, Jin X, Song Y, Zhang H, et al. Removal of Cd2+ from aqueous solution using graphene oxide modified activate carbon derived from peanut shell. Int J Agric & Biol Eng, 2023; 16(5): 226–235.
期刊介绍:
International Journal of Agricultural and Biological Engineering (IJABE, https://www.ijabe.org) is a peer reviewed open access international journal. IJABE, started in 2008, is a joint publication co-sponsored by US-based Association of Agricultural, Biological and Food Engineers (AOCABFE) and China-based Chinese Society of Agricultural Engineering (CSAE). The ISSN 1934-6344 and eISSN 1934-6352 numbers for both print and online IJABE have been registered in US. Now, Int. J. Agric. & Biol. Eng (IJABE) is published in both online and print version by Chinese Academy of Agricultural Engineering.