花生壳制备的氧化石墨烯改性活性炭去除水溶液中的Cd2+

IF 3.1 2区 农林科学 Q2 AGRICULTURAL ENGINEERING
Yilu Du, Hui Wang, Jiangtao Ji, Xin Jin, Yang Song, Hao Zhang, Zhi Chen
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引用次数: 3

摘要

以花生壳和天然石墨为原料,采用改进的Hummers法制备氧化石墨烯(GO),并通过共热解法制备氧化石墨烯改性花生壳活性炭复合材料(GO- ac)。采用响应面法(RSM)对活性炭的最佳制备条件进行筛选,优化制备工艺。结果表明:GO-AC表面微孔增多,比表面积增大,表面吸附位点增多,含氧官能团增多;吸附过程以化学吸附为主,吸附量分别是BC (45.16 mg/g)和AC (119.21 mg/g)的3.45倍和1.30倍。经过6次吸附-解吸循环试验,GO-AC对Cd2+的吸附量仍高达89.26 mg/g,比BC (19.18 mg/g)和AC (46.13 mg/g)分别提高了93.5%和365%,具有良好的可重复利用性。该研究为废弃生物质的高附加值转化提供了有益的参考,对Cd2+进行显著吸附改性的GO-AC负载作为一种新型低成本吸附剂具有良好的应用潜力。关键词:氧化石墨烯改性生物炭,响应面优化,吸附,重金属[DOI: 10.25165/ j.j ijabe.20231605.8046]引用本文:杜艳玲,王辉,季建涛,金鑫,宋勇,张辉,等。花生壳制备的氧化石墨烯改性活性炭去除水溶液中的Cd2+。农业与生物工程学报,2023;16(5): 226 - 235。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Removal of Cd2+ from aqueous solution using graphene oxide modified activate carbon derived from peanut shell
Graphene oxide (GO) was prepared by a modified Hummers method using peanut shells and natural graphite, and graphene oxide modified peanut shells activated carbon composites (GO-AC) were synthesized by co-pyrolysis. The optimal preparation conditions of AC were screened by response surface methodology (RSM) to optimize the preparation process. The results showed that the surface of GO-AC had more micropores and larger specific surface area, increased the surface adsorption sites and had more oxygen-containing functional groups. The adsorption process was mainly based on chemisorption, and the adsorption capacity was 3.45 and 1.30 times higher than that of BC (45.16 mg/g) and AC (119.21 mg/g), respectively. After six adsorption-desorption cycle tests, the adsorption amount of Cd2+ by GO-AC was still as high as 89.26 mg/g, with a percentage increase of 93.5% and 365% compared to BC (19.18 mg/g) and AC (46.13 mg/g), respectively, with good reusability. The research can provide a useful reference for the high value-added conversion of waste biomass, and GO-AC loading modified with significant adsorption of Cd2+ has good potential for application as a novel and low-cost adsorbent. Keywords: graphene oxide-modified biochar, response surface optimization, adsorption, heavy metal DOI: 10.25165/j.ijabe.20231605.8046 Citation: Du Y L, Wang H, Ji J T, Jin X, Song Y, Zhang H, et al. Removal of Cd2+ from aqueous solution using graphene oxide modified activate carbon derived from peanut shell. Int J Agric & Biol Eng, 2023; 16(5): 226–235.
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来源期刊
CiteScore
4.30
自引率
12.50%
发文量
88
审稿时长
24 weeks
期刊介绍: International Journal of Agricultural and Biological Engineering (IJABE, https://www.ijabe.org) is a peer reviewed open access international journal. IJABE, started in 2008, is a joint publication co-sponsored by US-based Association of Agricultural, Biological and Food Engineers (AOCABFE) and China-based Chinese Society of Agricultural Engineering (CSAE). The ISSN 1934-6344 and eISSN 1934-6352 numbers for both print and online IJABE have been registered in US. Now, Int. J. Agric. & Biol. Eng (IJABE) is published in both online and print version by Chinese Academy of Agricultural Engineering.
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