Synergistic Interface Modification of Electron-Beam-Evaporated NiOx for High-Performance Perovskite Solar Cells.

Nickel oxide (NiOx) is considered an ideal hole transport layer (HTL) in inverted perovskite solar cells (PSCs) due to its excellent carrier mobility and low cost. Electron-beam-evaporated NiOx (E-beam-NiOx) exhibits exceptional commercial potential due to its process compatibility. However, there are surface defects in E-beam-NiOx, which are incompatible with perovskite (PVK) and limit its development. In this work, we used [4-(3,6-dimethyl-9H-carbazol-9-yl)butyl]phosphonic acid (Me-4PACz) as a self-assembled monolayer (SAM) and l-α-glycerylphosphorylcholine (GPC) to double modify the buried interface of E-beam-NiOx films. SAM is used to modify interface defects of NiOx, while GPC improves the wetting property and uniformity of the interface. Under the joint modification of SAM and GPC, the interface defects of NiOx films were passivated, and the hole extraction ability of HTL was improved. At the same time, the growth quality of PVK films was improved, and the energy level matching between NiOx and PVK was optimized. After optimization, the small-area (0.0575 cm2) PSCs achieved a champion power conversion efficiency (PCE) of 23.31%, providing an effective strategy and direction for the preparation of high-efficiency PSCs by E-beam-NiOx.