覆盖特征：一种结构独特的{Fe(NO)2}10-{Fe(NO)2}9双核二硝基铁配合物，由μ-ƞ2-FBF3−配体桥接，n -杂环碳烯稳定

IF 3.7 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemistry - A European Journal Pub Date : 2025-10-23 DOI:10.1002/chem.70299

Yung-Chuan Chuang, Ching-Wen Lin, Yi-Hung Wu, Yu-Hsien Chang, Chung-Hung Hsieh

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引用次数: 0

摘要

天使般的图形持有由{Fe(NO) 2}10和{Fe(NO) 2}9单核前体形成的双核二硝基铁络合物（DNIC），体现了这种独特分子的优雅和精确。该配合物具有罕见的μ-η - 2- fbf₃桥和n -杂环碳烯的稳定作用，就像天使温柔的魔力之触，在配位化学中微妙地保持和平衡氧化还原力和结构力，协调电子和空间技巧。更多信息可以在c - h的研究文章中找到。Hsieh和同事（DOI: 10.1002/chem.202502404）。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Cover Feature: A Structurally Unique {Fe(NO)2}10-{Fe(NO)2}9 Dinuclear Dinitrosyl Iron Complex Bridged by a μ-ƞ2-FBF3− Ligand and Stabilized by N-Heterocyclic Carbenes

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Cover Feature: A Structurally Unique {Fe(NO)2}10-{Fe(NO)2}9 Dinuclear Dinitrosyl Iron Complex Bridged by a μ-ƞ2-FBF3− Ligand and Stabilized by N-Heterocyclic Carbenes

An angelic figure holds a dinuclear dinitrosyl iron complex (DNIC) formed from {Fe(NO)₂}¹⁰ and {Fe(NO)₂}⁹ mononuclear precursors, epitomizing the elegance and precision of this unique molecule. With its rare μ-η²-FBF₃ bridge and stabilization by N-heterocyclic carbenes, like an angel's gentle magic touch, the complex delicately holds and balances redox and structural forces in coordination chemistry, harmonizing electronic and steric finesse. More information can be found in the Research Article by C.-H. Hsieh and co-workers (DOI: 10.1002/chem.202502404).

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来源期刊

Chemistry - A European Journal 化学-化学综合

CiteScore

7.90

自引率

4.70%

发文量

1808

审稿时长

1.8 months

期刊介绍： Chemistry—A European Journal is a truly international journal with top quality contributions (2018 ISI Impact Factor: 5.16). It publishes a wide range of outstanding Reviews, Minireviews, Concepts, Full Papers, and Communications from all areas of chemistry and related fields. Based in Europe Chemistry—A European Journal provides an excellent platform for increasing the visibility of European chemistry as well as for featuring the best research from authors from around the world. All manuscripts are peer-reviewed, and electronic processing ensures accurate reproduction of text and data, plus short publication times. The Concepts section provides nonspecialist readers with a useful conceptual guide to unfamiliar areas and experts with new angles on familiar problems. Chemistry—A European Journal is published on behalf of ChemPubSoc Europe, a group of 16 national chemical societies from within Europe, and supported by the Asian Chemical Editorial Societies. The ChemPubSoc Europe family comprises: Angewandte Chemie, Chemistry—A European Journal, European Journal of Organic Chemistry, European Journal of Inorganic Chemistry, ChemPhysChem, ChemBioChem, ChemMedChem, ChemCatChem, ChemSusChem, ChemPlusChem, ChemElectroChem, and ChemistryOpen.