Rui Wang , Hao Chen , Dongtao Wang , Hiromi Nagaumi , Hao Shi , Minghe Zhang , Zibin Wu , Xiaozu Zhang , Pengfei Wang , Dongsheng Gao , Bo Zhang
{"title":"用微量锡诱导的高密度分散体提高铝硅铸造合金的高温蠕变性能","authors":"Rui Wang , Hao Chen , Dongtao Wang , Hiromi Nagaumi , Hao Shi , Minghe Zhang , Zibin Wu , Xiaozu Zhang , Pengfei Wang , Dongsheng Gao , Bo Zhang","doi":"10.1016/j.matchar.2025.115634","DOIUrl":null,"url":null,"abstract":"<div><div>As an important precipitation-strengthening phases in Al-Si cast aluminum alloys, submicron dispersoids still lack effective methods to sufficiently refine them and increase their number density. In this study, we introduce the trace Sn into an Al-7%Si-0.5%Mn cast alloy and employ non-isothermal heat treatment to simultaneously refine both Si and Mn-containing dispersoids. This approach reduces their average size by 28% and markedly increases the total number density of dispersoids by 2.4 times, thereby achieving a minimum secondary creep rate that is 74.1 % lower than that of the Sn-free alloy at 300 °C/25 MPa condition. The trace Sn produces more nucleation sites for the Si precipitates by combining more vacancies, and the high number-density Si precipitates promote the precipitation of Mn-containing dispersoids at high temperature. Moreover, after holding at 500 °C for 6 hours, the coarsening of Mn-containing dispersoids in the Sn-containing alloy is only 4.9 %. This study elucidates the mechanism by which the trace Sn enhances the dispersoid precipitation in the Al-Si cast alloy and provides a novel design strategy for high-temperature creep-resistant cast aluminum alloy.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"229 ","pages":"Article 115634"},"PeriodicalIF":5.5000,"publicationDate":"2025-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Improving high-temperature creep resistance in Al-Si cast alloy by trace Sn-induced high number density dispersoids\",\"authors\":\"Rui Wang , Hao Chen , Dongtao Wang , Hiromi Nagaumi , Hao Shi , Minghe Zhang , Zibin Wu , Xiaozu Zhang , Pengfei Wang , Dongsheng Gao , Bo Zhang\",\"doi\":\"10.1016/j.matchar.2025.115634\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>As an important precipitation-strengthening phases in Al-Si cast aluminum alloys, submicron dispersoids still lack effective methods to sufficiently refine them and increase their number density. In this study, we introduce the trace Sn into an Al-7%Si-0.5%Mn cast alloy and employ non-isothermal heat treatment to simultaneously refine both Si and Mn-containing dispersoids. This approach reduces their average size by 28% and markedly increases the total number density of dispersoids by 2.4 times, thereby achieving a minimum secondary creep rate that is 74.1 % lower than that of the Sn-free alloy at 300 °C/25 MPa condition. The trace Sn produces more nucleation sites for the Si precipitates by combining more vacancies, and the high number-density Si precipitates promote the precipitation of Mn-containing dispersoids at high temperature. Moreover, after holding at 500 °C for 6 hours, the coarsening of Mn-containing dispersoids in the Sn-containing alloy is only 4.9 %. This study elucidates the mechanism by which the trace Sn enhances the dispersoid precipitation in the Al-Si cast alloy and provides a novel design strategy for high-temperature creep-resistant cast aluminum alloy.</div></div>\",\"PeriodicalId\":18727,\"journal\":{\"name\":\"Materials Characterization\",\"volume\":\"229 \",\"pages\":\"Article 115634\"},\"PeriodicalIF\":5.5000,\"publicationDate\":\"2025-10-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Characterization\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1044580325009234\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CHARACTERIZATION & TESTING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Characterization","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1044580325009234","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CHARACTERIZATION & TESTING","Score":null,"Total":0}
Improving high-temperature creep resistance in Al-Si cast alloy by trace Sn-induced high number density dispersoids
As an important precipitation-strengthening phases in Al-Si cast aluminum alloys, submicron dispersoids still lack effective methods to sufficiently refine them and increase their number density. In this study, we introduce the trace Sn into an Al-7%Si-0.5%Mn cast alloy and employ non-isothermal heat treatment to simultaneously refine both Si and Mn-containing dispersoids. This approach reduces their average size by 28% and markedly increases the total number density of dispersoids by 2.4 times, thereby achieving a minimum secondary creep rate that is 74.1 % lower than that of the Sn-free alloy at 300 °C/25 MPa condition. The trace Sn produces more nucleation sites for the Si precipitates by combining more vacancies, and the high number-density Si precipitates promote the precipitation of Mn-containing dispersoids at high temperature. Moreover, after holding at 500 °C for 6 hours, the coarsening of Mn-containing dispersoids in the Sn-containing alloy is only 4.9 %. This study elucidates the mechanism by which the trace Sn enhances the dispersoid precipitation in the Al-Si cast alloy and provides a novel design strategy for high-temperature creep-resistant cast aluminum alloy.
期刊介绍:
Materials Characterization features original articles and state-of-the-art reviews on theoretical and practical aspects of the structure and behaviour of materials.
The Journal focuses on all characterization techniques, including all forms of microscopy (light, electron, acoustic, etc.,) and analysis (especially microanalysis and surface analytical techniques). Developments in both this wide range of techniques and their application to the quantification of the microstructure of materials are essential facets of the Journal.
The Journal provides the Materials Scientist/Engineer with up-to-date information on many types of materials with an underlying theme of explaining the behavior of materials using novel approaches. Materials covered by the journal include:
Metals & Alloys
Ceramics
Nanomaterials
Biomedical materials
Optical materials
Composites
Natural Materials.