Junkun Zhang , Li Jin , Zhongao Wang , Quanhui Li , Xiaoxue Yan , Ertao Lei , Kai Ma , Chao Lyu
{"title":"基于差分电压分析和马氏距离的锂离子电池组内部短路检测与定量评估","authors":"Junkun Zhang , Li Jin , Zhongao Wang , Quanhui Li , Xiaoxue Yan , Ertao Lei , Kai Ma , Chao Lyu","doi":"10.1016/j.ijoes.2025.101212","DOIUrl":null,"url":null,"abstract":"<div><div>Accurate and prompt diagnosis of internal short circuits at an early stage is critical for preventing severe safety incidents and ensuring the reliability and safety of lithium-ion batteries. However, existing early-stage internal short-circuit diagnosis methods often rely heavily on high-precision battery models and large volumes of high-quality labeled training data, limiting their practicality and robustness in real-world applications. To address these limitations, this paper proposes a novel method for early detection and quantitative assessment of internal short circuits in lithium-ion battery packs, based on differential voltage (DV) analysis and Mahalanobis distance. The proposed approach extracts a median DV curve from the sorted terminal voltages of individual cells within a battery pack, which serves as a reference to characterize the normal cell behavior. The Mahalanobis distance between each cell's DV curve and the reference curve is then calculated and compared against a threshold to distinguish short-circuited cells from healthy ones. For the identified faulty cells, the short-circuit current and resistance are estimated by analyzing the differences between charging voltage curves across adjacent cycles, enabling precise quantification of fault severity. Experimental validation is conducted using simulated internal short circuits with varying severities. Results show that the proposed method can accurately detect short-circuited cells when the short-circuit resistance is less than or equal to 300 Ω. The maximum and minimum relative errors of short-circuit resistance estimation are 5.21 % and 1.20 %, respectively, demonstrating the effectiveness and accuracy of the proposed method.</div></div>","PeriodicalId":13872,"journal":{"name":"International Journal of Electrochemical Science","volume":"20 11","pages":"Article 101212"},"PeriodicalIF":2.4000,"publicationDate":"2025-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Detection and quantitative assessment of internal short circuits in lithium-ion battery packs based on differential voltage analysis and mahalanobis distance\",\"authors\":\"Junkun Zhang , Li Jin , Zhongao Wang , Quanhui Li , Xiaoxue Yan , Ertao Lei , Kai Ma , Chao Lyu\",\"doi\":\"10.1016/j.ijoes.2025.101212\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Accurate and prompt diagnosis of internal short circuits at an early stage is critical for preventing severe safety incidents and ensuring the reliability and safety of lithium-ion batteries. However, existing early-stage internal short-circuit diagnosis methods often rely heavily on high-precision battery models and large volumes of high-quality labeled training data, limiting their practicality and robustness in real-world applications. To address these limitations, this paper proposes a novel method for early detection and quantitative assessment of internal short circuits in lithium-ion battery packs, based on differential voltage (DV) analysis and Mahalanobis distance. The proposed approach extracts a median DV curve from the sorted terminal voltages of individual cells within a battery pack, which serves as a reference to characterize the normal cell behavior. The Mahalanobis distance between each cell's DV curve and the reference curve is then calculated and compared against a threshold to distinguish short-circuited cells from healthy ones. For the identified faulty cells, the short-circuit current and resistance are estimated by analyzing the differences between charging voltage curves across adjacent cycles, enabling precise quantification of fault severity. Experimental validation is conducted using simulated internal short circuits with varying severities. Results show that the proposed method can accurately detect short-circuited cells when the short-circuit resistance is less than or equal to 300 Ω. The maximum and minimum relative errors of short-circuit resistance estimation are 5.21 % and 1.20 %, respectively, demonstrating the effectiveness and accuracy of the proposed method.</div></div>\",\"PeriodicalId\":13872,\"journal\":{\"name\":\"International Journal of Electrochemical Science\",\"volume\":\"20 11\",\"pages\":\"Article 101212\"},\"PeriodicalIF\":2.4000,\"publicationDate\":\"2025-10-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Electrochemical Science\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1452398125002883\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Electrochemical Science","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1452398125002883","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
Detection and quantitative assessment of internal short circuits in lithium-ion battery packs based on differential voltage analysis and mahalanobis distance
Accurate and prompt diagnosis of internal short circuits at an early stage is critical for preventing severe safety incidents and ensuring the reliability and safety of lithium-ion batteries. However, existing early-stage internal short-circuit diagnosis methods often rely heavily on high-precision battery models and large volumes of high-quality labeled training data, limiting their practicality and robustness in real-world applications. To address these limitations, this paper proposes a novel method for early detection and quantitative assessment of internal short circuits in lithium-ion battery packs, based on differential voltage (DV) analysis and Mahalanobis distance. The proposed approach extracts a median DV curve from the sorted terminal voltages of individual cells within a battery pack, which serves as a reference to characterize the normal cell behavior. The Mahalanobis distance between each cell's DV curve and the reference curve is then calculated and compared against a threshold to distinguish short-circuited cells from healthy ones. For the identified faulty cells, the short-circuit current and resistance are estimated by analyzing the differences between charging voltage curves across adjacent cycles, enabling precise quantification of fault severity. Experimental validation is conducted using simulated internal short circuits with varying severities. Results show that the proposed method can accurately detect short-circuited cells when the short-circuit resistance is less than or equal to 300 Ω. The maximum and minimum relative errors of short-circuit resistance estimation are 5.21 % and 1.20 %, respectively, demonstrating the effectiveness and accuracy of the proposed method.
期刊介绍:
International Journal of Electrochemical Science is a peer-reviewed, open access journal that publishes original research articles, short communications as well as review articles in all areas of electrochemistry: Scope - Theoretical and Computational Electrochemistry - Processes on Electrodes - Electroanalytical Chemistry and Sensor Science - Corrosion - Electrochemical Energy Conversion and Storage - Electrochemical Engineering - Coatings - Electrochemical Synthesis - Bioelectrochemistry - Molecular Electrochemistry