M. D. Tugushev, I. A. Nikovskii, S. A. Solov’eva, Yu. V. Nelyubina
{"title":"乙酰吡啶基吡唑酮与钴（II）水配合物的合成","authors":"M. D. Tugushev, I. A. Nikovskii, S. A. Solov’eva, Yu. V. Nelyubina","doi":"10.1134/S107032842460150X","DOIUrl":null,"url":null,"abstract":"<p>The reaction of the new bidentate ligand, 4-acetyl-2-phenyl-5-(pyridin-2-yl)-2,4-dihydro-3<i>H</i>-pyrazol-3-one (L), with cobalt(II) acetate in the presence of diazabicycloundecene as a base affords the mononuclear cobalt(II) aqua complex CoL<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>. The product of its crystallization from a DMF–water mixture (CoL<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>·2MeOH·2H<sub>2</sub>O) after drying in vacuo is characterized by X-ray diffraction (XRD), as well as the initial acetylpyrazolone L (CIF files CCDC nos. 2400710 and 2400711, respectively). The <i>cis</i> configuration of the ligands in the formed aqua complex and the presence of solvate methanol molecules in the complex (methanol was not a component of the mixture of solvents for crystallization) indicate that the complex is the product of solvolysis with water of the intermediate oxocubane complex Co<sub>4</sub>O<sub>4</sub>.</p>","PeriodicalId":759,"journal":{"name":"Russian Journal of Coordination Chemistry","volume":"51 7","pages":"653 - 661"},"PeriodicalIF":1.1000,"publicationDate":"2025-10-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of the Cobalt(II) Aqua Complex with Acetylpyridylpyrazolone\",\"authors\":\"M. D. Tugushev, I. A. Nikovskii, S. A. Solov’eva, Yu. V. Nelyubina\",\"doi\":\"10.1134/S107032842460150X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The reaction of the new bidentate ligand, 4-acetyl-2-phenyl-5-(pyridin-2-yl)-2,4-dihydro-3<i>H</i>-pyrazol-3-one (L), with cobalt(II) acetate in the presence of diazabicycloundecene as a base affords the mononuclear cobalt(II) aqua complex CoL<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>. The product of its crystallization from a DMF–water mixture (CoL<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>·2MeOH·2H<sub>2</sub>O) after drying in vacuo is characterized by X-ray diffraction (XRD), as well as the initial acetylpyrazolone L (CIF files CCDC nos. 2400710 and 2400711, respectively). The <i>cis</i> configuration of the ligands in the formed aqua complex and the presence of solvate methanol molecules in the complex (methanol was not a component of the mixture of solvents for crystallization) indicate that the complex is the product of solvolysis with water of the intermediate oxocubane complex Co<sub>4</sub>O<sub>4</sub>.</p>\",\"PeriodicalId\":759,\"journal\":{\"name\":\"Russian Journal of Coordination Chemistry\",\"volume\":\"51 7\",\"pages\":\"653 - 661\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2025-10-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Coordination Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S107032842460150X\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Coordination Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S107032842460150X","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
Synthesis of the Cobalt(II) Aqua Complex with Acetylpyridylpyrazolone
The reaction of the new bidentate ligand, 4-acetyl-2-phenyl-5-(pyridin-2-yl)-2,4-dihydro-3H-pyrazol-3-one (L), with cobalt(II) acetate in the presence of diazabicycloundecene as a base affords the mononuclear cobalt(II) aqua complex CoL2(H2O)2. The product of its crystallization from a DMF–water mixture (CoL2(H2O)2·2MeOH·2H2O) after drying in vacuo is characterized by X-ray diffraction (XRD), as well as the initial acetylpyrazolone L (CIF files CCDC nos. 2400710 and 2400711, respectively). The cis configuration of the ligands in the formed aqua complex and the presence of solvate methanol molecules in the complex (methanol was not a component of the mixture of solvents for crystallization) indicate that the complex is the product of solvolysis with water of the intermediate oxocubane complex Co4O4.
期刊介绍：
Russian Journal of Coordination Chemistry is a journal that publishes reviews, original papers, and short communications on all aspects of theoretical and experimental coordination chemistry. Modern coordination chemistry is an interdisciplinary science that makes a bridge between inorganic, organic, physical, analytical, and biological chemistry.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
