以1-乙基-3-甲基咪唑辛酸酯为直接溶剂纺制麦秸浆纤维素多丝

Antje Ota , Marc P. Vocht , Ronald Beyer , André van Zomeren , Ilona van Zandvoort , Jaap W. van Hal , Frank Hermanutz
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引用次数: 0

摘要

对人造纤维素纤维的需求正在迅速增加;然而,这些纤维主要是基于木材溶解纸浆。生长更快的作物,如农业残留物和一年生快速生长的植物(如大麻),也是有吸引力的替代原料。利用麦草浆(WS)纺制基于离子液体纺丝技术的连续人造纤维素纤维。用丙酮基有机溶剂分馏得到的漂白和未漂白的WS纸浆生产长丝,以硬木(HW)为基准纸浆,采用新型干喷湿纺丝(HighPerCell®工艺)技术,以1-乙基-3-甲基咪唑辛酸盐([C2C1im] [Oc])为溶剂纺连续长丝。用该方法纺出了连续多丝长丝和高技术质量长丝。拉伸伸长率达9%,拉伸强度达35 cN/tex。这种新方法还允许制备适合纺织应用的低湿纤化纤维长丝。应该强调的是,在长丝的生产和可持续制浆技术中只使用了回收的IL。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Spinning of wheat straw-based pulp into cellulosic multifilaments by 1-Ethyl-3-methylimidazolium octanoate as direct solvent
The demand for man-made cellulosic fibers is rapidly increasing; however, these fibers are mainly based on wood dissolving pulp. Faster growing crops, such as agricultural residues and annual fast-growing plants (i.e. hemp), are attractive alternative raw materials as well.e report on the use of wheat straw pulp (WS) for the spinning of continuous man-made cellulosic fibers based on an ionic liquid spinning technology. Filaments were produced from bleached and unbleached WS pulp that were obtained by an acetone based organosolv fractionation Commercial dissolving pulp based on hardwood (HW) was used as reference pulp Continuous filaments were spun using a novel dry-jet wet spinning (HighPerCell® process) technique, which is based on the use of 1-ethyl-3-methylimidazolium octanoate ( [C2C1im] [Oc]) as a solvent. Via this approach, continuous multifilament filaments were spun in textile and technical quality filament yarns. Elongation at break up to 9 % and tenacities of 35 cN/tex were obtained for the WS filaments. The novel approach also allows the preparation of low wet fibrillating cellulosic filaments appropriate for textile applications. It should be emphasized that only recycled IL was used in the production of the filaments and sustainable pulping technology.
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CiteScore
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