Qi Zhang , Cong Zhang , Dafang Wang , Ziwei Hao , Shiqin Chen , Bingbing Hu , Xuan Liang
{"title":"基于电化学阻抗模型的锂离子电池多频动力学非迭代参数辨识","authors":"Qi Zhang , Cong Zhang , Dafang Wang , Ziwei Hao , Shiqin Chen , Bingbing Hu , Xuan Liang","doi":"10.1016/j.jpowsour.2025.238533","DOIUrl":null,"url":null,"abstract":"<div><div>Accurate and efficient parameter identification is essential for lithium-ion battery management and detection applications, as it enables precise state estimation, fault diagnosis, and quality assessment. However, conventional iterative identification methods suffer from long computation times, while deep learning-based approaches require extensive training, making them impractical for applications demanding rapid and real-time parameter acquisition. To address these challenges, this paper proposes a novel EIS-based non-iterative parameter identification method, which directly maps kinetic parameters to impedance characteristics using a simplified electrochemical impedance model. By eliminating iterative calculations and training overhead, the proposed method significantly improves identification speed while maintaining high accuracy. Experimental results show that it achieves a relative mean absolute error below 1 % and 6 % for negative and positive electrode impedance simulations, respectively. Furthermore, parameter consistency is validated by applying the identified parameters to time-domain electrochemical model simulations, yielding a root mean square error of 1.63 mV under high-frequency custom pulse conditions and 34.07 mV under dynamic stress test conditions. These results demonstrate the method's strong potential for real-time battery state estimation and efficient parameter identification in battery management systems, as well as rapid quality assessment in production lines.</div></div>","PeriodicalId":377,"journal":{"name":"Journal of Power Sources","volume":"661 ","pages":"Article 238533"},"PeriodicalIF":7.9000,"publicationDate":"2025-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Non-iterative parameter identification for lithium-ion battery kinetics across multiple frequency ranges via electrochemical impedance model\",\"authors\":\"Qi Zhang , Cong Zhang , Dafang Wang , Ziwei Hao , Shiqin Chen , Bingbing Hu , Xuan Liang\",\"doi\":\"10.1016/j.jpowsour.2025.238533\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Accurate and efficient parameter identification is essential for lithium-ion battery management and detection applications, as it enables precise state estimation, fault diagnosis, and quality assessment. However, conventional iterative identification methods suffer from long computation times, while deep learning-based approaches require extensive training, making them impractical for applications demanding rapid and real-time parameter acquisition. To address these challenges, this paper proposes a novel EIS-based non-iterative parameter identification method, which directly maps kinetic parameters to impedance characteristics using a simplified electrochemical impedance model. By eliminating iterative calculations and training overhead, the proposed method significantly improves identification speed while maintaining high accuracy. Experimental results show that it achieves a relative mean absolute error below 1 % and 6 % for negative and positive electrode impedance simulations, respectively. Furthermore, parameter consistency is validated by applying the identified parameters to time-domain electrochemical model simulations, yielding a root mean square error of 1.63 mV under high-frequency custom pulse conditions and 34.07 mV under dynamic stress test conditions. These results demonstrate the method's strong potential for real-time battery state estimation and efficient parameter identification in battery management systems, as well as rapid quality assessment in production lines.</div></div>\",\"PeriodicalId\":377,\"journal\":{\"name\":\"Journal of Power Sources\",\"volume\":\"661 \",\"pages\":\"Article 238533\"},\"PeriodicalIF\":7.9000,\"publicationDate\":\"2025-10-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Power Sources\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0378775325023699\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Power Sources","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0378775325023699","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Non-iterative parameter identification for lithium-ion battery kinetics across multiple frequency ranges via electrochemical impedance model
Accurate and efficient parameter identification is essential for lithium-ion battery management and detection applications, as it enables precise state estimation, fault diagnosis, and quality assessment. However, conventional iterative identification methods suffer from long computation times, while deep learning-based approaches require extensive training, making them impractical for applications demanding rapid and real-time parameter acquisition. To address these challenges, this paper proposes a novel EIS-based non-iterative parameter identification method, which directly maps kinetic parameters to impedance characteristics using a simplified electrochemical impedance model. By eliminating iterative calculations and training overhead, the proposed method significantly improves identification speed while maintaining high accuracy. Experimental results show that it achieves a relative mean absolute error below 1 % and 6 % for negative and positive electrode impedance simulations, respectively. Furthermore, parameter consistency is validated by applying the identified parameters to time-domain electrochemical model simulations, yielding a root mean square error of 1.63 mV under high-frequency custom pulse conditions and 34.07 mV under dynamic stress test conditions. These results demonstrate the method's strong potential for real-time battery state estimation and efficient parameter identification in battery management systems, as well as rapid quality assessment in production lines.
期刊介绍:
The Journal of Power Sources is a publication catering to researchers and technologists interested in various aspects of the science, technology, and applications of electrochemical power sources. It covers original research and reviews on primary and secondary batteries, fuel cells, supercapacitors, and photo-electrochemical cells.
Topics considered include the research, development and applications of nanomaterials and novel componentry for these devices. Examples of applications of these electrochemical power sources include:
• Portable electronics
• Electric and Hybrid Electric Vehicles
• Uninterruptible Power Supply (UPS) systems
• Storage of renewable energy
• Satellites and deep space probes
• Boats and ships, drones and aircrafts
• Wearable energy storage systems