高温、高矿化度、低渗透油藏提高采收率纳米乳液的实验研究及性能

IF 4.3 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
ACS Omega Pub Date : 2025-10-08 DOI:10.1021/acsomega.5c08116
Yan Zhang, , , Dingxue Zhang*, , , Yong Wang, , , Jun Chen, , , Mengke Xin, , , Qirui Zhang, , , Yiwei Qin, , and , Linshuo Yan, 
{"title":"高温、高矿化度、低渗透油藏提高采收率纳米乳液的实验研究及性能","authors":"Yan Zhang,&nbsp;, ,&nbsp;Dingxue Zhang*,&nbsp;, ,&nbsp;Yong Wang,&nbsp;, ,&nbsp;Jun Chen,&nbsp;, ,&nbsp;Mengke Xin,&nbsp;, ,&nbsp;Qirui Zhang,&nbsp;, ,&nbsp;Yiwei Qin,&nbsp;, and ,&nbsp;Linshuo Yan,&nbsp;","doi":"10.1021/acsomega.5c08116","DOIUrl":null,"url":null,"abstract":"<p >Nanoemulsion has significant application potential in enhancing oil recovery in low-permeability reservoirs due to its unique nanoscale size and excellent interfacial properties. In this paper, a novel nanoemulsion flooding system was prepared by a microemulsion dilution method, using nonionic surfactant fatty alcohol polyoxyethylene ether (AEO-9), zwitterionic surfactant cocoamidopropyl hydroxy sulfobetaine (CHSB), liquid paraffin, oleic acid, n-butanol, and aqueous sodium tosylate. The key performance parameters, such as droplet size, interfacial tension (IFT), and wettability, were evaluated in the laboratory, and the oil displacement performance of the nanoemulsion was assessed through an oil-washing ability experiment and a displacement experiment. The results showed that the droplet size of the nanoemulsion system was 30–50 nm. It has ultralow IFT (&lt;1 × 10<sup>–2</sup> mN/m) and could change the core surface from hydrophobic to hydrophilic, maintaining emulsion stability even at a high temperature of 100 °C. Through the displacement experiment, the nanoemulsion demonstrated the characteristics of “rapid breakthrough-high-efficiency transport” (diffusion coefficient of 5.086 × 10<sup>–4</sup> cm<sup>2</sup>/s). Finally, an additional oil recovery of 17.71% was achieved when the nanoemulsion injection concentration was 0.30 wt % and the injection volume was 0.4 PV. The nanoemulsion system using aqueous sodium tosylate (NaOTs) as the continuous phase exhibits both high-salt tolerance and high-temperature hydrolysis resistance, making it suitable for nanoemulsion flooding in high-temperature, high-salt reservoirs. This paper aids in selecting the optimal nano-oil displacement agent for enhanced oil recovery (EOR) projects in high-temperature, high-salinity, low-permeability reservoirs and promotes the application of nanoemulsions in oil fields.</p>","PeriodicalId":22,"journal":{"name":"ACS Omega","volume":"10 41","pages":"49136–49147"},"PeriodicalIF":4.3000,"publicationDate":"2025-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acsomega.5c08116","citationCount":"0","resultStr":"{\"title\":\"Experimental Study on a Nanoemulsion for EOR in High-Temperature, High-Salinity, Low-Permeability Reservoirs and Its Performance\",\"authors\":\"Yan Zhang,&nbsp;, ,&nbsp;Dingxue Zhang*,&nbsp;, ,&nbsp;Yong Wang,&nbsp;, ,&nbsp;Jun Chen,&nbsp;, ,&nbsp;Mengke Xin,&nbsp;, ,&nbsp;Qirui Zhang,&nbsp;, ,&nbsp;Yiwei Qin,&nbsp;, and ,&nbsp;Linshuo Yan,&nbsp;\",\"doi\":\"10.1021/acsomega.5c08116\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Nanoemulsion has significant application potential in enhancing oil recovery in low-permeability reservoirs due to its unique nanoscale size and excellent interfacial properties. In this paper, a novel nanoemulsion flooding system was prepared by a microemulsion dilution method, using nonionic surfactant fatty alcohol polyoxyethylene ether (AEO-9), zwitterionic surfactant cocoamidopropyl hydroxy sulfobetaine (CHSB), liquid paraffin, oleic acid, n-butanol, and aqueous sodium tosylate. The key performance parameters, such as droplet size, interfacial tension (IFT), and wettability, were evaluated in the laboratory, and the oil displacement performance of the nanoemulsion was assessed through an oil-washing ability experiment and a displacement experiment. The results showed that the droplet size of the nanoemulsion system was 30–50 nm. It has ultralow IFT (&lt;1 × 10<sup>–2</sup> mN/m) and could change the core surface from hydrophobic to hydrophilic, maintaining emulsion stability even at a high temperature of 100 °C. Through the displacement experiment, the nanoemulsion demonstrated the characteristics of “rapid breakthrough-high-efficiency transport” (diffusion coefficient of 5.086 × 10<sup>–4</sup> cm<sup>2</sup>/s). Finally, an additional oil recovery of 17.71% was achieved when the nanoemulsion injection concentration was 0.30 wt % and the injection volume was 0.4 PV. The nanoemulsion system using aqueous sodium tosylate (NaOTs) as the continuous phase exhibits both high-salt tolerance and high-temperature hydrolysis resistance, making it suitable for nanoemulsion flooding in high-temperature, high-salt reservoirs. This paper aids in selecting the optimal nano-oil displacement agent for enhanced oil recovery (EOR) projects in high-temperature, high-salinity, low-permeability reservoirs and promotes the application of nanoemulsions in oil fields.</p>\",\"PeriodicalId\":22,\"journal\":{\"name\":\"ACS Omega\",\"volume\":\"10 41\",\"pages\":\"49136–49147\"},\"PeriodicalIF\":4.3000,\"publicationDate\":\"2025-10-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.acs.org/doi/pdf/10.1021/acsomega.5c08116\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Omega\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acsomega.5c08116\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Omega","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsomega.5c08116","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

摘要

纳米乳液以其独特的纳米级尺寸和优异的界面特性,在低渗透油藏中提高采收率具有重要的应用潜力。以非离子表面活性剂脂肪醇聚氧乙烯醚(AEO-9)、两性离子表面活性剂cocoamidopropyl hydrohydrosulfobetaine (CHSB)、液体石蜡、油酸、正丁醇、烟酸钠为原料,采用微乳液稀释法制备了新型纳米乳液驱替体系。在实验室中对纳米乳液的关键性能参数(如液滴尺寸、界面张力(IFT)和润湿性)进行了评价,并通过洗油能力实验和驱油实验对纳米乳液的驱油性能进行了评价。结果表明,纳米乳液体系的粒径为30 ~ 50 nm。它具有超低的IFT (<1 × 10-2 mN/m),可以使岩心表面由疏水变为亲水,即使在100℃的高温下也能保持乳液稳定性。通过驱替实验,纳米乳具有“快速突破-高效输运”的特点(扩散系数为5.086 × 10-4 cm2/s)。最后,当纳米乳液注入浓度为0.30 wt %,注入体积为0.4 PV时,可获得17.71%的额外采收率。以水基甲苯磺酸钠(NaOTs)为连续相的纳米乳液体系具有高耐盐性和耐高温水解性,适用于高温、高盐油藏的纳米乳液驱。为高温、高矿化度、低渗透油藏提高采收率选择最佳纳米驱油剂,促进纳米乳液在油田中的应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Experimental Study on a Nanoemulsion for EOR in High-Temperature, High-Salinity, Low-Permeability Reservoirs and Its Performance

Nanoemulsion has significant application potential in enhancing oil recovery in low-permeability reservoirs due to its unique nanoscale size and excellent interfacial properties. In this paper, a novel nanoemulsion flooding system was prepared by a microemulsion dilution method, using nonionic surfactant fatty alcohol polyoxyethylene ether (AEO-9), zwitterionic surfactant cocoamidopropyl hydroxy sulfobetaine (CHSB), liquid paraffin, oleic acid, n-butanol, and aqueous sodium tosylate. The key performance parameters, such as droplet size, interfacial tension (IFT), and wettability, were evaluated in the laboratory, and the oil displacement performance of the nanoemulsion was assessed through an oil-washing ability experiment and a displacement experiment. The results showed that the droplet size of the nanoemulsion system was 30–50 nm. It has ultralow IFT (<1 × 10–2 mN/m) and could change the core surface from hydrophobic to hydrophilic, maintaining emulsion stability even at a high temperature of 100 °C. Through the displacement experiment, the nanoemulsion demonstrated the characteristics of “rapid breakthrough-high-efficiency transport” (diffusion coefficient of 5.086 × 10–4 cm2/s). Finally, an additional oil recovery of 17.71% was achieved when the nanoemulsion injection concentration was 0.30 wt % and the injection volume was 0.4 PV. The nanoemulsion system using aqueous sodium tosylate (NaOTs) as the continuous phase exhibits both high-salt tolerance and high-temperature hydrolysis resistance, making it suitable for nanoemulsion flooding in high-temperature, high-salt reservoirs. This paper aids in selecting the optimal nano-oil displacement agent for enhanced oil recovery (EOR) projects in high-temperature, high-salinity, low-permeability reservoirs and promotes the application of nanoemulsions in oil fields.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信