猪肉衍生的多孔碳超级电容器:实现“近零损耗”和超长循环寿命

IF 4.3 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
ACS Omega Pub Date : 2025-10-13 DOI:10.1021/acsomega.5c08616
Haoyang Peng, , , Huihua Li, , , Yulei Liu, , , Han Zhang, , , Ziwen Wang, , and , Minjie Wang*, 
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引用次数: 0

摘要

虽然生物质衍生碳材料在储能领域已经得到了广泛的探索,但以动物蛋白为前体的研究相对较少,其潜在价值尚未得到充分开发。本研究以猪肉为原料,磷酸二淀粉为添加剂,经过复合、炭化、KOH活化等工艺,制备了富氧蛋白基生物质多孔炭。其中,APE-2样品氧含量高达9.81%,具有以微孔为主的分层微介孔结构,单位比表面积(SSA)为1599 m2 g-1,孔体积为0.692 cm3 g-1。在6 M KOH作为电解液的三电极电池中,它在1 a g-1下表现出565 F - 1的可逆比电容以及出色的倍率能力,即使在35 a g-1下也保持474 F - 1的比电容。当使用6 M KOH作为电极材料组装对称超级电容器(SCs)时,它在0.5 a g-1下获得了250 F - 1的显著可逆电容性能,在20 a g-1下保持在143 F - 1。它还表现出超稳定的循环行为,几乎“零衰减”,20000次循环后电容保持率为99.7%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Pork-Derived Porous Carbon for Supercapacitors: Achieving “Near-Zero-Loss” and Ultralong Cycle Life

While biomass-derived carbon materials have been extensively explored in the field of energy storage, research focusing on animal protein as a precursor remains relatively scarce, and its potential value is yet to be fully exploited. In this study, oxygen-rich protein-based biomass porous carbons were prepared using pork as the raw material and phosphate distarch as the additive via a strategy involving compositing, subsequent carbonization, and KOH activation. Among these carbons, sample APE-2 possessed a high oxygen content of 9.81%, a hierarchical micromesoporous structure dominated by micropores, specific surface area (SSA) per unit amount of 1599 m2 g–1, and pore volume at 0.692 cm3 g–1. Under a three-electrode cell where 6 M KOH functions as the electrolyte, it demonstrated an excellent reversible specific capacitance of 565 F g–1 under 1 A g–1 as well as outstanding rate capability, maintaining a specific capacitance of 474 F g–1 even at 35 A g–1. When utilized as electrode materials to assemble symmetric supercapacitors (SCs) using 6 M KOH, it achieved a prominent reversible specific capacitive performance at 250 F g–1 under 0.5 A g–1 as well as remained at 143 F g–1 under 20 A g–1. It also exhibits an ultrastable cycling behavior with nearly “zero decay” as evidenced by a capacitance retention of 99.7% after 20,000 cycles.

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来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
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