二硒化物/二硫化物与重氮盐偶联反应的电化学催化

IF 2.7 4区化学 Q1 CHEMISTRY, ORGANIC

Asian Journal of Organic Chemistry Pub Date : 2025-10-01 DOI:10.1002/ajoc.202500549

Haoxiang Zhang , Chaolin Li , Peiyuan Luo , Fei Ji , Changquan Zhang , Yuhan Jin , Yonghong Mi , Peng Liu , Qiyue Liu , Xiao Zhang

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引用次数: 0

摘要

描述了一种电化学催化的二硒化物/二硫化物与重氮盐的偶联反应。该方法具有反应时间短、反应条件温和、成本低、效率高、无金属催化剂等特点，为有机硒化合物的合成提供了一条新的途径。循环伏安法（CV）、分裂细胞实验、开关电实验和自由基捕获反应等机理研究支持了重氮盐与二硒化物交叉偶联过程的电化学催化作用。

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Electrochemical Catalysis of Coupling Reaction between Diselenide / Disulfide and Diazonium Salt

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Electrochemical Catalysis of Coupling Reaction between Diselenide / Disulfide and Diazonium Salt

An electrochemically catalyzed coupling reaction of diselenides/disulfides with diazonium salts has been described. This method features short reaction time, mild conditions, low cost, high efficiency, and metal‐catalyst‐free operation, providing a novel route for synthesizing organoselenium compounds. Mechanistic studies such as cyclic voltammetry (CV), divided cell experiment, on–off electricity experiment, and radical trapping reactions support the electrochemical catalysis of the cross‐coupling process of diselenides with diazonium salts.

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来源期刊

Asian Journal of Organic Chemistry CHEMISTRY, ORGANIC-

CiteScore

4.70

自引率

3.70%

发文量

372

期刊介绍： Organic chemistry is the fundamental science that stands at the heart of chemistry, biology, and materials science. Research in these areas is vigorous and truly international, with three major regions making almost equal contributions: America, Europe and Asia. Asia now has its own top international organic chemistry journal—the Asian Journal of Organic Chemistry (AsianJOC) The AsianJOC is designed to be a top-ranked international research journal and publishes primary research as well as critical secondary information from authors across the world. The journal covers organic chemistry in its entirety. Authors and readers come from academia, the chemical industry, and government laboratories.