封面:Ni/光氧化还原C-N偶联中的分子杂化催化剂:“分批”和“流动”辐照技术的比较(ChemCatChem 20/2025)

IF 3.9 3区 化学 Q2 CHEMISTRY, PHYSICAL
ChemCatChem Pub Date : 2025-10-19 DOI:10.1002/cctc.70377
Violetta A. Ionova, Dr. Elizaveta V. Ermakova, Kirill S. Zazerin, Dr. Anton S. Abel, Dr. Vladislav M. Korshunov, Dr. Ilya V. Taydakov, Dr. Vitaly A. Roznyatovsky, Dr. Alexei D. Averin, Prof. Irina P. Beletskaya
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引用次数: 0

摘要

封面说明了两种光催化剂在芳基卤化物的Ni/光氧化还原胺化反应中的不同效率。光催化剂被描绘成性格各异的猫。当“流动”照射时,更活跃的经典铱光催化剂产生镍纳米粒子(NiNPs)和镍黑,导致催化系统失活。活性较低的杂化钌光催化剂提供了最佳的镍还原速率;因此,催化系统是更有效的。更多信息可以在V. A. Ionova, A. S. Abel, I. P. Beletskaya及其同事的研究文章中找到(DOI: 10.1002/cctc.202500964)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Front Cover: Molecular Hybrid Catalysts in Ni/Photoredox C–N Coupling: Comparison of “in Batch” and “in Flow” Irradiation Techniques (ChemCatChem 20/2025)

Front Cover: Molecular Hybrid Catalysts in Ni/Photoredox C–N Coupling: Comparison of “in Batch” and “in Flow” Irradiation Techniques (ChemCatChem 20/2025)

The Front Cover illustrates the different efficiency of two photocatalysts in the Ni/photoredox amination of arylhalides. Photocatalysts are depicted as cats with different characters. When irradiated “in flow”, the more active, classical iridium photocatalyst produces nickel nanoparticles (NiNPs) and nickel black, which leads to deactivation of the catalytic system. The less active, hybrid ruthenium photocatalyst provides an optimal rate of nickel reduction; as a result, the catalytic system is more effective. More information can be found in the Research Article by V. A. Ionova, A. S. Abel, I. P. Beletskaya and co-workers (DOI: 10.1002/cctc.202500964).

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来源期刊
ChemCatChem
ChemCatChem 化学-物理化学
CiteScore
8.10
自引率
4.40%
发文量
511
审稿时长
1.3 months
期刊介绍: With an impact factor of 4.495 (2018), ChemCatChem is one of the premier journals in the field of catalysis. The journal provides primary research papers and critical secondary information on heterogeneous, homogeneous and bio- and nanocatalysis. The journal is well placed to strengthen cross-communication within between these communities. Its authors and readers come from academia, the chemical industry, and government laboratories across the world. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies, and is supported by the German Catalysis Society.
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