腐植酸作为C-S键构建的天然催化剂：脱羧和脱羧硫醚合成

IF 4.6 3区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

RSC Advances Pub Date : 2025-10-16 DOI:10.1039/D5RA05889A

Maral Salehi, Najmeh Nowrouzi and Mohammad Abbasi

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引用次数: 0

摘要

本研究介绍了腐植酸作为一种可持续的、绿色的C-S键形成催化剂。在二甲基甲酰胺（DMF）中，硫醇与醛和羧酸反应合成了硫醚，其中腐植酸有效地促进了稳定的巯基和烷基自由基的生成。该方法温和、高效、环保，具有广泛的官能团耐受性，突出了腐植酸在绿色有机合成中作为实用催化剂的潜力。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Humic acid as a natural catalyst for C–S bond construction: decarbonylative and decarboxylative thioether synthesis

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Humic acid as a natural catalyst for C–S bond construction: decarbonylative and decarboxylative thioether synthesis

In this study, humic acid is introduced as a sustainable and green catalyst for C–S bond formation. Thioethers were synthesized via the reaction of thiols with aldehydes and carboxylic acids in dimethylformamide (DMF), where humic acid effectively facilitated the generation of stable thiyl and alkyl radicals. This method offers a mild, efficient, and environmentally friendly approach with broad functional group tolerance, highlighting the potential of humic acid as a practical catalyst in green organic synthesis.

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来源期刊

RSC Advances chemical sciences-

CiteScore

7.50

自引率

2.60%

发文量

3116

审稿时长

1.6 months

期刊介绍： An international, peer-reviewed journal covering all of the chemical sciences, including multidisciplinary and emerging areas. RSC Advances is a gold open access journal allowing researchers free access to research articles, and offering an affordable open access publishing option for authors around the world.