Ru(II)-催化醇转移乙烯化反应。

IF 6.6 2区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

ChemSusChem Pub Date : 2025-10-17 DOI:10.1002/cssc.202501279

Saša Opačak, Sergey Tin

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引用次数: 0

摘要

以烷基乙烯醚为乙烯化剂，研究了钌催化剂在醇转移乙烯化反应中的应用。发现双（2-甲基烯丙基）（1,5-环二烯）钌（II）在许多伯醇上进行有效的反应，并在仲醇的转移乙烯化反应中提供平均产率。回收实验表明，所有反应组分均可分离，分离出的乙基乙烯醚可作为乙烯化剂重复使用，无不良影响。

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Ru(II)-Catalyzed Transfer Vinylation of Alcohols.

Ruthenium catalysts are investigated for the transfer vinylation of alcohols using alkyl vinyl ethers as the vinylating agents. Bis(2-methylallyl)(1,5-cycloocta-diene)ruthenium(II) is found to perform the reaction efficiently on many primary alcohols and affords average yields in the transfer vinylation of secondary alcohols. A recycling experiment carried out shows that all reaction components can be separated and that the isolated ethyl vinyl ether can be reused as the vinylating agent without detrimental effect.

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来源期刊

ChemSusChem 化学-化学综合

CiteScore

15.80

自引率

4.80%

发文量

555

审稿时长

1.8 months

期刊介绍： ChemSusChem Impact Factor (2016): 7.226 Scope: Interdisciplinary journal Focuses on research at the interface of chemistry and sustainability Features the best research on sustainability and energy Areas Covered: Chemistry Materials Science Chemical Engineering Biotechnology