烯烃加氢酯化的研究进展

IF 23.5 1区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Coordination Chemistry Reviews Pub Date : 2025-10-17 DOI:10.1016/j.ccr.2025.217273

Ruoqian Zhang, Xingyong Wang, Hongchen Li, Lu Wang, Wanru Feng, Songbao Fu

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引用次数: 0

摘要

烯烃加氢酯化反应是由烯烃、一氧化碳（CO）和醇合成高价值酯的关键原子经济反应，由于其在增塑剂、药品和聚合物中间体中的工业应用而引起了极大的关注。这篇综合综述系统地概述了催化策略的最新进展，重点是均相系统，特别是配体工程（氮配体，单齿，双齿和多齿膦配体）和酸启动子，以提高活性，区域选择性和立体选择性在不同底物上。替代CO源的创新减轻了对有毒CO气体的依赖，而多相和双相系统解决了催化剂的回收和可持续性。未来的发展方向是强调绿色化学整合、生物质原料利用和工业过程优化，以实现可持续的酯合成。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Research progress in alkene hydroesterification

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Research progress in alkene hydroesterification

Alkene hydroesterification, a pivotal atom-economical reaction for synthesizing high-value esters from alkenes, carbon monoxide (CO), and alcohols, has garnered significant attention due to its industrial applications in plasticizers, pharmaceuticals, and polymer intermediates. This comprehensive review systematically outlines recent advances in catalytic strategies, focusing on homogeneous systems, particularly ligand engineering (nitrogen ligands, mono-, bi-, and multidentate phosphines ligands) and acid promoters to enhance activity, regioselectivity, and stereoselectivity across diverse substrates. Innovations in alternative CO sources mitigate reliance on toxic CO gas, while heterogeneous and biphasic systems address catalyst recovery and sustainability. Future directions emphasize green chemistry integration, biomass-derived feedstock utilization, and industrial process optimization for sustainable ester synthesis.

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来源期刊

Coordination Chemistry Reviews 化学-无机化学与核化学

CiteScore

34.30

自引率

5.30%

发文量

457

审稿时长

54 days

期刊介绍： Coordination Chemistry Reviews offers rapid publication of review articles on current and significant topics in coordination chemistry, encompassing organometallic, supramolecular, theoretical, and bioinorganic chemistry. It also covers catalysis, materials chemistry, and metal-organic frameworks from a coordination chemistry perspective. Reviews summarize recent developments or discuss specific techniques, welcoming contributions from both established and emerging researchers. The journal releases special issues on timely subjects, including those featuring contributions from specific regions or conferences. Occasional full-length book articles are also featured. Additionally, special volumes cover annual reviews of main group chemistry, transition metal group chemistry, and organometallic chemistry. These comprehensive reviews are vital resources for those engaged in coordination chemistry, further establishing Coordination Chemistry Reviews as a hub for insightful surveys in inorganic and physical inorganic chemistry.