Fernanda C. Bastos, Wellington da Conceição Lobato do Nascimento, Cáritas J. S. Mendonça, Rafaely N. Lima, Fernando C. Silva, Adeilton P. Maciel
{"title":"椰油中月桂酸甲酯的选择性分离及特性研究","authors":"Fernanda C. Bastos, Wellington da Conceição Lobato do Nascimento, Cáritas J. S. Mendonça, Rafaely N. Lima, Fernando C. Silva, Adeilton P. Maciel","doi":"10.1002/ejlt.70058","DOIUrl":null,"url":null,"abstract":"<p><i>Syagrus cocoides</i> Martius is a palm tree species. Its fruits are composed of an oily almond, until now restricted only to popular use. On the basis of that, to contribute scientific information about this plant, this work evaluated the physical Ariri coconut characteristic, the physical–chemical specifications of almond oil, and its potential to selectively obtain the lauric methyl ester from the transesterification oil reaction. Cold and hot oil extraction was performed using hexane as solvent, producing 18% and 14%, respectively. Alkaline transesterification was conducted for 1 h, and total conversion was observed. Conducting the ester separation by classic column chromatography, the effective isolation of lauric methyl ester in a 93% purity and 27% isolated yield was obtained. The results of this study contribute to knowledge regarding an under-explored species. Furthermore, they facilitate the development of sustainable methodologies for obtaining valuable oleochemical products.</p><p><i>Practical Applications</i>: This study demonstrates the potential of the Ariri coconut as an alternative source of oil and raw material for the production of standard lauric methyl ester, a substance of high commercial value. The findings of this study indicate that <i>Syagrus cocoides</i> Martius, Ariri, is a promising species due to its comparable oil content to other palm species, suggesting the potential for the production of various fatty acid esters. The fractionation of lauric acid ester by column chromatography was effective and selective, indicating a new route for the production of analytical standards or inputs for the fine chemicals industry.</p>","PeriodicalId":11988,"journal":{"name":"European Journal of Lipid Science and Technology","volume":"127 10","pages":""},"PeriodicalIF":1.8000,"publicationDate":"2025-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejlt.70058","citationCount":"0","resultStr":"{\"title\":\"Selective Isolation and Characterization of Lauric Methyl Ester From Ariri Coconut (Syagrus cocoides Martius) Fatty Oil\",\"authors\":\"Fernanda C. Bastos, Wellington da Conceição Lobato do Nascimento, Cáritas J. S. Mendonça, Rafaely N. Lima, Fernando C. Silva, Adeilton P. Maciel\",\"doi\":\"10.1002/ejlt.70058\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><i>Syagrus cocoides</i> Martius is a palm tree species. Its fruits are composed of an oily almond, until now restricted only to popular use. On the basis of that, to contribute scientific information about this plant, this work evaluated the physical Ariri coconut characteristic, the physical–chemical specifications of almond oil, and its potential to selectively obtain the lauric methyl ester from the transesterification oil reaction. Cold and hot oil extraction was performed using hexane as solvent, producing 18% and 14%, respectively. Alkaline transesterification was conducted for 1 h, and total conversion was observed. Conducting the ester separation by classic column chromatography, the effective isolation of lauric methyl ester in a 93% purity and 27% isolated yield was obtained. The results of this study contribute to knowledge regarding an under-explored species. Furthermore, they facilitate the development of sustainable methodologies for obtaining valuable oleochemical products.</p><p><i>Practical Applications</i>: This study demonstrates the potential of the Ariri coconut as an alternative source of oil and raw material for the production of standard lauric methyl ester, a substance of high commercial value. The findings of this study indicate that <i>Syagrus cocoides</i> Martius, Ariri, is a promising species due to its comparable oil content to other palm species, suggesting the potential for the production of various fatty acid esters. The fractionation of lauric acid ester by column chromatography was effective and selective, indicating a new route for the production of analytical standards or inputs for the fine chemicals industry.</p>\",\"PeriodicalId\":11988,\"journal\":{\"name\":\"European Journal of Lipid Science and Technology\",\"volume\":\"127 10\",\"pages\":\"\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2025-08-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ejlt.70058\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"European Journal of Lipid Science and Technology\",\"FirstCategoryId\":\"97\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ejlt.70058\",\"RegionNum\":3,\"RegionCategory\":\"农林科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"FOOD SCIENCE & TECHNOLOGY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"European Journal of Lipid Science and Technology","FirstCategoryId":"97","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ejlt.70058","RegionNum":3,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"FOOD SCIENCE & TECHNOLOGY","Score":null,"Total":0}
Selective Isolation and Characterization of Lauric Methyl Ester From Ariri Coconut (Syagrus cocoides Martius) Fatty Oil
Syagrus cocoides Martius is a palm tree species. Its fruits are composed of an oily almond, until now restricted only to popular use. On the basis of that, to contribute scientific information about this plant, this work evaluated the physical Ariri coconut characteristic, the physical–chemical specifications of almond oil, and its potential to selectively obtain the lauric methyl ester from the transesterification oil reaction. Cold and hot oil extraction was performed using hexane as solvent, producing 18% and 14%, respectively. Alkaline transesterification was conducted for 1 h, and total conversion was observed. Conducting the ester separation by classic column chromatography, the effective isolation of lauric methyl ester in a 93% purity and 27% isolated yield was obtained. The results of this study contribute to knowledge regarding an under-explored species. Furthermore, they facilitate the development of sustainable methodologies for obtaining valuable oleochemical products.
Practical Applications: This study demonstrates the potential of the Ariri coconut as an alternative source of oil and raw material for the production of standard lauric methyl ester, a substance of high commercial value. The findings of this study indicate that Syagrus cocoides Martius, Ariri, is a promising species due to its comparable oil content to other palm species, suggesting the potential for the production of various fatty acid esters. The fractionation of lauric acid ester by column chromatography was effective and selective, indicating a new route for the production of analytical standards or inputs for the fine chemicals industry.
期刊介绍:
The European Journal of Lipid Science and Technology is a peer-reviewed journal publishing original research articles, reviews, and other contributions on lipid related topics in food science and technology, biomedical science including clinical and pre-clinical research, nutrition, animal science, plant and microbial lipids, (bio)chemistry, oleochemistry, biotechnology, processing, physical chemistry, and analytics including lipidomics. A major focus of the journal is the synthesis of health related topics with applied aspects.
Following is a selection of subject areas which are of special interest to EJLST:
Animal and plant products for healthier foods including strategic feeding and transgenic crops
Authentication and analysis of foods for ensuring food quality and safety
Bioavailability of PUFA and other nutrients
Dietary lipids and minor compounds, their specific roles in food products and in nutrition
Food technology and processing for safer and healthier products
Functional foods and nutraceuticals
Lipidomics
Lipid structuring and formulations
Oleochemistry, lipid-derived polymers and biomaterials
Processes using lipid-modifying enzymes
The scope is not restricted to these areas. Submissions on topics at the interface of basic research and applications are strongly encouraged. The journal is the official organ the European Federation for the Science and Technology of Lipids (Euro Fed Lipid).